Publication List(2004)

Lewis Acid Catalysis in Supercritical Carbon Dioxide (scCO2). Use of Poly(ethyleneglycol) Derivatives and Perfluoroalkylbenzenes as Surfactant Molecules which Enable Efficient Catalysis in scCO2,
I. Komoto, S. Kobayashi,
J. Org. Chem., 69, 680-688 (2004).


Copper(II)-Catalyzed Highly Enantioselective Addition of Enamides to Imines: The Use of Enamides as Nucleophiles in Asymmetric Catalysis,
R. Matsubara, Y. Nakamura, S. Kobayashi,
Angew. Chem. Int. Ed., 43, 1679-1681 (2004).


Phosphine Oxides as Efficient Neutral Coordinate-Organocatalysts for Stereoselective Allylations of N-Acylhydrazones,
C. Ogawa, H. Konishi, M. Sugiura, S. Kobayashi,
Org. Biomol. Chem., 2, 446-448 (2004).


Air-Stable, Storable, and Highly Efficient Chiral Zirconium Catalysts for Enantioselective Mannich-type, aza Diels-Alder, Aldol, and Hetero Diels-Alder Reactions,
S. Kobayashi, M. Ueno, S, Saito, Y. Mizuki, H. Ishitani, Y. Yamashita,
Proc. Natl. Acad. Sci. U.S.A., 101, 5476-5481 (2004).


Iron(III) Chloride as a Water-compatible Lewis Acid for Diastereoselective Aldol Reactions in Water in the Presence of a Surfactant,
N. Aoyama, K. Manabe, S. Kobayashi,
Chem. Lett., 33, 312-313 (2004).


Recoverable, Reusable, Highly Active, and Sulfur-tolerant Polymer Incarcerated Palladium for Hydrogenation,
K. Okamoto, R. Akiyama, S. Kobayashi,
J. Org. Chem., 69, 2871-2873 (2004).


A Microfluidic Device for Conducting Gas-Liquid-Solid Hydrogenation Reactions,
J. Kobayashi, Y. Mori, K. Okamoto, R. Akiyama, M. Ueno, T. Kitamori, S. Kobayashi,
Science, 304, 1305-1308 (2004).
Abstract Full text


Catalytic Asymmetric Synthesis of α-Amino Phosphonates Using Enantioselective Carbon-Carbon Bond-Forming Reactions,
S. Kobayashi, H. Kiyohara, Y. Nakamura, R. Matsubara,
J. Am. Chem. Soc., 126, 6558-6559 (2004).


Suzuki-Miyaura Coupling Catalyzed by the Polymer Incarcerated Palladium (PI Pd), a Highly Active Recoverable and Reusable Pd Catalyst,
K. Okamoto, R. Akiyama, S. Kobayashi,
Org. Lett., 6, 1987-1990 (2004).


Highly Diastereo- and Enantioselective Reactions of Enecarbamates with Ethyl Glyoxylate Leading to Both Optically Active Syn- and Anti-α-alkyl-β-hydroxy Imines and Ketones,
R. Matsubara, Y. Nakamura, S. Kobayashi,
Angew. Chem. Int. Ed., 43, 3258-3260 (2004).


Hydrophobic polymer-supported scandium catalyst for carbon-carbon bond-forming reactions in water,
S. Iimura, K. Manabe, S. Kobayashi,
Tetrahedron, 60, 7673-7678 (2004).


α-Aminoallylation of Aldehydes with Ammonia: Stereoselective Synthesis of Homoallylic Primary Amines,
M. Sugiura, K. Hirano, S. Kobayashi,
J. Am. Chem. Soc., 126, 7182-7183 (2004).


Enantio- and Diastereoselective, Stereospecific Mannich-type Reactions in Water,
T. Hamada, K. Manabe, S. Kobayashi,
J. Am. Chem. Soc.,126, 7768-7769 (2004).


Catalytic Enantio- and Diastereoselective Aldol Reactions of Glycine-Derived Silicon Enolate with Aldehydes: An Efficient Approach to the Asymmetric Synthesis of Anti-β-Hydroxy-α-Amino Acid Derivatives,
J. Kobayashi, M. Nakamura, Y. Mori, Y. Yamashita, S. Kobayashi,
J. Am. Chem. Soc.,126, 9192-9193 (2004).


Zirconium-Catalyzed Enantioselective [3+2] Cycloaddition of Hydrazones to Olefins Leading to Optically Active Pyrazolidine, Pyrazoline, and 1,3-Diamine Derivatives,
Y. Yamashita, S. Kobayashi,
J. Am. Chem. Soc., 126, 11279-11282 (2004).


Neutral Coordinate-Organocatalysts in Organic Synthesis: Allylation of Acylhydrazones with Allyltrichlorosilanes,
S. Kobayashi, M. Sugiura, C. Ogawa,
Adv. Synth. Catal., 346, 1023-1034 (2004).


Efficient Synthesis of N-Acyl-α-Amino Acids via Polymer Incarcerated Palladium-Catalyzed Amidocarbonylation,
R. Akiyama, T. Sagae, M. Sugiura, S. Kobayashi,
J. Organomet. Chem., 689, 3806-3809 (2004).


Highly Diastereo- and Enantioselective Reactions of Enecarbamates with an Aldehyde,
R. Matsubara, P. Vital, Y. Nakamura, H. Kiyohara, S. Kobayashi,
Tetrahedron, 60, 9769-9784 (2004).


Catalytic Asymmetric Hydroxymethylation of Silicon Enolates Using an Aqueous Solution of Formaldehyde with a Chiral Scandium Complex,
S. Ishikawa, T. Hamada, K. Manabe, S. Kobayashi,
J.Am. Chem. Soc., 126, 12236-12237 (2004).


Stereospecific, Enantioselective Allylation of a-Hydrazono Esters Using Allyltrichlorosilanes with BINAP Dioxides as Neutral-Coordinate Organocatalysts,
C. Ogawa, M. Sugiura, S. Kobayashi,
Angew. Chem., Int. Ed. Engl., 116, 6653-6655 (2004).