Publication List(2006)

Chiral Scandium Catalysts for Enantioselective Michael Reactions of β-Ketoesters

C. Ogawa, K. Kizu, H. Shimizu, M. Takeuchi and S. Kobayashi

Chem. Asian J., 1, 121-124 (2006). DOI: 10.1002/asia.200600093

Divide et Impera - Multiphase, green solvent and immobilization strategies for molecular catalysis

RT Baker, S. Kobayashi, W. Leitner

Adv. Synth & Catal., 348, 1337-1340 (2006). DOI: 10.1002/adsc.200600344

Highly Selective Formation of Both Propargyl- and Allenyltrichlorosilanes and Their Regiospecific Addition to Various Types of Aldehydes: Highly Selective Preparation of Allenic and Homopropargylic Alcohols,
U. Schneider, M. Sugiura, S. Kobayashi,
Tetrahedron, 62 , 496-502 (2006).

Catalytic Asymmetric Mannich-type Reactions in Aqueous Media Activated by ZnF 2 －Chiral Diamine,
T. Hamada, K. Manabe, S. Kobayashi,
Chem. Eur. J., 12 , 1205-1215 (2006).

Practical Preparation Method of Polymer Incarcerated (PI) Palladium Catalysts Using Pd(II) Salts,
H. Hagio, M. Sugiura, S. Kobayashi,
Org. Lett , 8 , 375-378 (2006).

Highly Selective Preparation of Allenic and Homopropargylic Hydrazides Through Regiospecific Addition of Propargyltrichlorosilane and Allenyltrichlorosilane to Various Types of N -Acylhydrazones,
U. Schneider, M. Sugiura, S. Kobayashi,
Adv. Synth. Catal., 348 , 323-329 (2006).

Dehydrative Glycosylation in Water Using a Br?nsted Acid－Surfactant-Combined Catalyst,
N. Aoyama, S. Kobayashi,
Chem. Lett ., 35 , 238-239 (2006).

Enantiomerically enriched allylglycine derivatives through the catalytic asymmetric allylation of iminoesters and iminophosphonates with allylsilanes,
H. Kiyohara, Y. Nakamura, R. Matsubara, S. Kobayashi,
Angew. Chem. Int. Ed. , 45 , 1615-1617 (2006).

Semi-hydrogenation of Alkynes Using Phosphinated Polymer Incarcerated (PI) Palladium Catalysts,
R. Nishio, M. Sugiura S. Kobayashi,
Org. Biomol. Chem ., 4 , 992-995 (2006).

Multiphase Organic Synthesis in Microchannel Reactors,
J. Kobayashi, Y. Mori, S. Kobayashi,
Chem. Asian J .1 , 22-35 (2006).

Catalytic Enantioselective and Diastereoselective Addition of Aldehyde-Derived Enecarbamates toα-Oxo Aldehydes,
R. Matsubara, N. Kawai, S. Kobayashi,
Angew. Chem. Int. Ed. ,45 , 3814-3816 (2006).

With Molecular-Oxygen-Activated Lewis Acids: Dinuclear Molybdenum Complexes for Aza-Diels-Alder Reactions of Acyl Hydrazones,
Y. Yamashita, M. M. Salter, K. Aoyama, S. Kobayashi,
Angew. Chem. Int. Ed. , 45 , 3816-3819 (2006).

Synthesis of Acridone Derivatives Using Polymer-Supported Palladium and Scandium Catalysts,
R. Nishio, S. Wessely, M. Sugiura, S. Kobayashi,
J. Combi. Chem.8 , 459-461 (2006).

Ag(I) Catalyzed Michael Additions of β -Ketoesters to Nitroalkenes in Water: Remarkable Effect of Water as a Reaction Medium on Reaction Rates,
S. Shirakawa, S. Kobayashi,
Synlett , 2006, 1410-1412.

Highly anti -Selective Catalytic Aldol Reactions of Amides with Aldehydes,
S. Saito, S. Kobayashi,
J. Am. Chem. Soc. 128 , 8704-8705 (2006).

New Entries to Water-Compatible Lewis Acids,
S. Kobayashi, C. Ogawa,
Chem. Eur. J.,12 , 5954 - 5960 (2006).

Chiral Scandium-Catalyzed Enantioselective Michael Reactions of β-Keto Esters,
C. Ogawa, K. Kizu, H. Shimizu, M. Takeuchi, S. Kobayashi,
Chem. Asian J.1 , 121-124 (2006).

Practical Access to the Polymer Incarcerated Platinum (PI Pt) Catalyst and Its Application to Hydrogenation,
Y. Miyazaki, H. Hagio, M. Sugiura, S. Kobayashi,
Org. Biomol. Chem.4 , 2529-2531 (2006).

A 100 Gram-Scale Production of a Key Building Block of Antibacterial Vancomycin: The Use of an Air-Stable Chiral Zirconium Catalyst and Complete Recovery of a Silicon Source in Catalytic Asymmetric Mukaiyama Aldol Reaction,
T. Isoda, R. Akiyama, H. Oyamada, S. Kobayashi,
Adv. Synth. Catal ., 348 , 1813-1817 (2006).

Remarkably Stable Chiral Zirconium Complexes for Asymmetric Mannich-type Reactions,
K. Saruhashi, S. Kobayashi,
J. Am. Chem. Soc ., 128 , 11232-11235 (2006).

Direct-type Catalytic Three-Component Mannich Reactions Leading to an Efficient Synthesis of α,β-Diamino Acid Derivatives,
M. M. Salter, J. Kobayashi, Y. Shimizu, S. Kobayashi ,
Org. Lett ., 8 , 3533-3536 (2006).

Immobilization of Osmium Catalysts for Asymmetric Dihydroxylation of Olefins,
S. Kobayahshi, M. Sugiura,
Adv. Synth. Catal ., 348 , 1496-1504 (2006).

Polysilane-Supported Pd and Pt Nanoparticles as Efficient Catalysts for Organic Synthesis,
H. Oyamada, R. Akiyama, H. Hagio, T. Naito, S. Kobayashi,
Chem. Commun .,2006, 4297-4299.

Enantioselective Transfer Aminoallylation: Synthesis of Optically Active Homoallylic Primary Amines,
M. Sugiura, C. Mori, S. Kobayashi,
J. Am. Chem. Soc ., 128 , 11038-11039 (2006).

Novel Immobilization Method of Enzymes Using a Hydrophilic Polymer Support,
J. Kobayashi, Y. Mori, S. Kobayashi,
Chem. Commun ., 2006 , 4227-4229.

A Heterogeneous Silica-Supported Scandium/Ionic Liquid Catalyst System for Organic Reactions in Water,
Y. Gu, C. Ogawa, J. Kobayashi, Y. Mori, S. Kobayashi,
Angew. Chem. Int. Ed .,45 , 7217-7220 (2006).

Chiral Scandium-catalysed Enantioselective Ring-Opening of meso -Epoxides with N -Heterocycle, Alcohol and Thiol Derivatives in Water,
M. Boudou, C. Ogawa, S. Kobayashi,
Adv. Synth. Catal .,348 , 2585-2589 (2006).

Carboxylic Acid-Catalyzed Three-Component Aza-Friedel-Crafts Reactions in Water for the Synthesis of 3-Substituted Indoles,
S. Shirakawa, S. Kobayashi,
Org. Lett ., 8 , 4939-4942 (2006).

Novel Hydrophobic Br?nsted Acidic Ionic-Liquids as Efficient and Reusable Catalysts for Organic Reactions in Water,
Y. Gu, C. Ogawa, S. Kobayashi,
Chem. Lett ., 35 , 1176-1177 (2006).

Enecarbamates as Imine Surrogates: Nucleophilic Addition of 1,3-Dicarbonyl Compounds to Enecarbamates,
S. Kobayashi, T. Gustafsson, Y. Shimizu, H. Kiyohara, R. Matsubara,
Org. Lett. , 8 , 4923-4925 (2006).

High Turnover Frequency Observed in Catalytic Enantioselective Addition Reactions of Enecarbamates and Enamides with Iminophosphonates,
H. Kiyohara, R. Matsubara, S. Kobayashi,
Org. Lett ., 8 , 5333-5335 (2006).

Catalytic Asymmetric Amination of Enecarbamates,
R. Matsubara, S. Kobayashi,
Angew. Chem. Int. Ed ., 45 , 7993-7995 (2006).