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学術論文 2024
Substrate-Dependent Role of a Pd Dopant in PdAu12 Catalysts in the Oxidation of p-Substituted Benzyl Alcohols: Promotion of Hydride Abstraction and Reductive Activation of O2
Shinya Masuda*, Haru Hirai, Pei Zhao, Shinjiro Takano, Masahiro Ehara, and Tatsuya Tsukuda*
ACS Catal., 14, 17123-17131 (2024).
Resistance of a PdAu12(8e) Core to Growth in Collision-Induced Sequential Reductive Elimination of (C≡CR)2 from [PdAu24(C≡CR)18]2-
Shun Ito, Koto Hirano, Kiichirou Koyasu, Xian-Kai Wan, Quan-Ming Wang, and Tatsuya Tsukuda*
J. Phys. Chem. Lett., 15, 11060-11066 (2024).
Carbon-supported Au25 cluster catalysts partially decorated with dendron thiolates: enhanced loading weight and durability for hydrogen evolution reaction
Kosuke Sakamoto, Shinya Masuda, Shinjiro Takano, and Tatsuya Tsukuda*
Nanoscale, 16, 20608-20616 (2024).
Metal nanoclusters, Open Access
Blue Shift of Localized Surface Plasmon Resonance of Gold Ultrathin Nanorod by Forming a Single Atomic Silver Shell via Antigalvanic Process
Subarna Maity, Toshiki Komagata, Shinjiro Takano, Shinya Masuda, Jun Kikkawa, Koji Kimoto, Koji Harano*, and Tatsuya Tsukuda*
Nano Lett., 24, 13206-13212 (2024).
Selected as Supplementary Cover Image
Tuning Photoluminescence Properties of Au Clusters by Surface Modification and Doping: Lessons from Case Studies of Icosahedral Au13
Dennis Alexander Buschmann, Haru Hirai, and Tatsuya Tsukuda*
Inorg. Chem. Front., 11, 6694-6710 (2024).
Invited Review
Selected as HOT Articles
Revisiting the structure of [PdAu9(PPh3)8(CN)]2+ produced by atmospheric pressure plasma irradiation of [PdAu8(PPh3)8]2+ in methanol
Takumi Imagawa, Shun Ito, Frank Hennrich, Marco Neumaier, Patrick Weis, Kiichirou Koyasu, Manfred M. Kappes*, and Tatsuya Tsukuda*
J. Chem. Phys., 161, 024303 (2024).
Gas-Phase Anion Photoelectron Spectroscopy of Alkanethiolate-Protected PtAu12 Superatoms: Charging Energy in Vacuum vs Solution
Yuriko Tasaka, Megumi Suyama, Shun Ito, Kiichirou Koyasu, Manfred Kappes*, Flavio Maran*, and Tatsuya Tsukuda*
Angew. Chem., Int. Ed., 63, e202408335 (2024).
Open Access
Selected as Hot Paper
Gas-Phase Structures of [Au21(SR)14]– and [Au17(SR)10]– with Eight Electrons: Can They Support an Icosahedral Au13 Core?
Yuki Fujiwara, Shun Ito, Kiichirou Koyasu, and Tatsuya Tsukuda*
J. Phys. Chem. A, 128, 3119-3125 (2024).
Cyclic ion mobility of doped [MAu24L18]2– superatoms and their fragments (M = Ni, Pd and Pt; L = alkynyl)
Frank Hennrich, Shun Ito, Patrick Weis, Marco Neumaier, Shinjiro Takano, Tatsuya Tsukuda, and Manfred M. Kappes*
Phys. Chem. Chem. Phys., 26, 8408-8418 (2024).
N-Heterocyclic Carbene-Stabilized Atomically Precise Metal Nanoclusters
Emily L. Albright, Tetyana I. Levchenko, Viveka K. Kulkarni, Angus I. Sullivan, Joseph F. DeJesus, Sami Malola, Shinjiro Takano, Masakazu Nambo*, Kevin Stamplecoskie*, Hannu Häkkinen*, Tatsuya Tsukuda*, and Cathleen M. Crudden*
J. Am. Chem. Soc., 146, 5759-5780 (2024).
Invited Perspective
Diphosphine-Protected IrAu12 Superatom with Open Site(s): Synthesis and Programmed Stepwise Assembly
Yuto Fukumoto†, Tsubasa Omoda†, Haru Hirai, Shinjiro Takano, Koji Harano, and Tatsuya Tsukuda* (†: Equal contribution)
Angew. Chem., Int. Ed., 63, e202402025 (2024).
Open Access
Featured in ChemistryViews
Introducing Iodide Ligands on IrAu12 Cluster Enhances Phosphorescence Efficiency and Photoredox Activity
Haru Hirai, Shinjiro Takano, Shinya Masuda, and Tatsuya Tsukuda*
ChemElectroChem, 11, e202300669 (2024).
Flavio Maran Festschrift, Open Access
Pt-doped Ru nanoparticles loaded on 'black gold' plasmonic nanoreactors as air stable reduction catalysts
Gunjan Sharma, Rishi Verma, Shinya Masuda, Khaled Mohamed Badawy, Nirpendra Singh, Tatsuya Tsukuda*, and Vivek Polshettiwar*
Nature Communications, 15, 713 (2024).
Open Access
Enantiopure Chiral Au13 Nanoclusters Stabilized by Ditopic N-Heterocyclic Carbenes: Synthesis, Characterization, and Electrocatalytic Reduction of CO2
Emily L. Albright, Sami Malola, Samuel I. Jacob, Hong Yi, Shinjiro Takano, Koichi Mimura, Tatsuya Tsukuda*, Hannu Häkkinen*, Masakazu Nambo*, and Cathleen M. Crudden*
Chem. Matter., 36, 1279-1289 (2024).
Atomically precise Au and Ag nanoclusters doped with single atom as model alloy catalysts
Shinya Masuda, Kosuke Sakamoto, and Tatsuya Tsukuda*
Nanoscale, 16, 4514-4528 (2024).
Invited Minireview, Open Access
Selected as Front Cover
Bonding and Electronic Interactions of Hydrogen with Gold Superatoms
Subarna Maity, Shinjiro Takano, Shinya Masuda, and Tatsuya Tsukuda*
J. Phys. Chem. C, 128, 19-30 (2024).
Invited Perspective
Selected as Supplementary Cover Image