論文・学会発表 | 高野 慎二郎
原著論文
- "Diving into Unknown Waters: Water-Soluble Clickable Au13 Nanoclusters Protected with N-Heterocyclic Carbenes for Bio-Medical Applications"
Angus I. Sullivan, Emily A. Steele, Shinjiro Takano, Elham Zeinizade, Juan Chen, Sami Malola, Kumar Siddhant, Hannu Häkkinen*, Kevin G. Stamplecoskie*, Tatsuya Tsukuda*, Gang Zheng*, Cathleen M. Crudden*
J. Am. Chem. Soc. (2024), in press. - "Impact of Ligand Structure on Biological Activity and Photophysical Properties of NHC-Protected Au13 Nanoclusters"
Viveka K. Kulkarni, Emily L. Albright, Elham Zeinizade, Emily Steele, Juan Chen, Lili Ding, Sami Malola, Shinjiro Takano, Kristen Harrington, Nahyun Kwon, Tetyana I. Levchenko, Masakazu Nambo*, Tatsuya Tsukuda*, Hannu Häkkinen*, Kevin Stamplecoskie*, Gang Zheng*, and Cathleen M. Crudden*
J. Am. Chem. Soc. (2024), in press. - "Substrate-Dependent Role of a Pd Dopant in PdAu12 Catalysts in the Oxidation of p-Substituted Benzyl Alcohols: Promotion of Hydride Abstraction and Reductive Activation of O2"
Shinya Masuda*, Haru Hirai, Pei Zhao, Shinjiro Takano, Masahiro Ehara, and Tatsuya Tsukuda*
ACS Catal., 14, 17123-17131 (2024). - "Carbon-supported Au25 cluster catalysts partially decorated with dendron thiolates: enhanced loading weight and durability for hydrogen evolution reaction"
Kosuke Sakamoto, Shinya Masuda, Shinjiro Takano, and Tatsuya Tsukuda*
Nanoscale, 16, 20608-20616 (2024). - "Blue Shift of Localized Surface Plasmon Resonance of Gold Ultrathin Nanorod by Forming a Single Atomic Silver Shell via Antigalvanic Process"
Subarna Maity, Toshiki Komagata, Shinjiro Takano, Shinya Masuda, Jun Kikkawa, Koji Kimoto, Koji Harano*, and Tatsuya Tsukuda*
Nano Lett., 24, 13206-13212 (2024). - "Cyclic ion mobility of doped [MAu24L18]2- superatoms and their fragments (M = Ni, Pd and Pt; L = alkynyl)"
Frank Hennrich, Shun Ito, Patrick Weis, Marco Neumaier, Shinjiro Takano, Tatsuya Tsukuda, and Manfred M. Kappes*
Phys. Chem. Chem. Phys., 26, 8408-8418 (2024). - "Diphosphine-Protected IrAu12 Superatom with Open Site(s): Synthesis and Programmed Stepwise Assembly"
Yuto Fukumoto, Tsubasa Omoda, Haru Hirai, Shinjiro Takano, Koji Harano, and Tatsuya Tsukuda*
Angew. Chem., Int. Ed., 63, e202402025 (2024). - "Introducing Iodide Ligands on IrAu12 Cluster Enhances Phosphorescence Efficiency and Photoredox Activity"
Haru Hirai, Shinjiro Takano, Shinya Masuda, and Tatsuya Tsukuda*
ChemElectroChem, 11, e202300669 (2024). - "Enantiopure Chiral Au13 Nanoclusters Stabilized by Ditopic N-Heterocyclic Carbenes: Synthesis, Characterization, and Electrocatalytic Reduction of CO2"
Emily L. Albright, Sami Malola, Samuel I. Jacob, Hong Yi, Shinjiro Takano, Koichi Mimura, Tatsuya Tsukuda*, Hannu Häkkinen*, Masakazu Nambo*, and Cathleen M. Crudden*
Chem. Mater., 36, 1279-1289 (2024). - "Clarifying the Electronic Structure of Anion-Templated Silver Nanoclusters by Optical Absorption Spectroscopy and Theoretical Calculation"
Yusuke Horita, Sakiat Hossain*, Mai Ishimi, Pei Zhao, Miyu Sera, Tokuhisa Kawawaki, Shinjiro Takano, Yoshiki Niihori, Toshikazu Nakamura, Tatsuya Tsukuda, Masahiro Ehara*, and Yuichi Negishi*
J. Am. Chem. Soc., 145, 23533-23540 (2023). - "Au13 Superatom Bearing Two Terpyridines at Coaxial Positions: Photoluminescence Quenching via Complexation with 3d Metal Ions"
Naoki Kito, Shinjiro Takano, Shinya Masuda, Koji, Harano, and Tatsuya Tsukuda*
Bull. Chem. Soc. Jpn., 96, 1045-1051 (2023). - "Collision-Induced Fission of Oblate Gold Superatom in [Au9(PPh3)8]3+: Deformation-Mediated Mechanism"
Satoru Muramatsu*, Yuki Nakahigashi, Tsubasa Omoda, Shinjiro Takano, Tatsuya Tsukuda*, and Yoshiya Inokuchi*
J. Phys. Chem. Lett., 14, 5641-5647 (2023). - "Synthesis and Characterization of a Monodentate N-Heterocyclic Carbene-Protected Au11-Nanocluster via Reduction with KC8"
Angus I. Sullivan, Joseph F. DeJesus, Sami Malola, Shinjiro Takano, Tatsuya Tsukuda*, Hannu Häkkinen*, and Cathleen M. Crudden*
Chem. Mater., 35, 2790-2796 (2023). - "Bioconjugation of Au25 Nanocluster to Monoclonal Antibody at Tryptophan"
Katarzyna Joanna Malawska, Shinjiro Takano, Kounosuke Oisaki*, Haruaki Yanagisawa, Masahide Kikkawa, Tatsuya Tsukuda, and Motomu Kanai*
Bioconjugate Chem., 34, 781-788 (2023). - "Effect of Group-10 Element M (Ni, Pd, Pt) on Electronic Structure of Icosahedral M@Au12 Cores of MAu24L18 (L = Alkynyl, Thiolate)"
Shinjiro Takano*, Emi Ito, Toshikazu Nakamura, and Tatsuya Tsukuda*
J. Phys. Chem. C, 127, 4360-4366 (2023). - "Partially Thiolated Au25 Cluster Anchored on Carbon Support via Noncovalent Ligand-Support Interactions: Active and Robust Catalyst for Aerobic Oxidation of Alcohols"
Kosuke Sakamoto, Shinya Masuda, Shinjiro Takano, and Tatsuya Tsukuda*
ACS Catal., 13, 3263-3271 (2023). - "IrAu12 superatom modified by chiral diphosphines: Doping-induced enhancement of chiroptical activity"
Haru Hirai, Takuya Nakashima*, Shinjiro Takano, Yukatsu Shichibu, Katsuaki Konishi*, Tsuyoshi Kawai, and Tatsuya Tsukuda*
J. Mater. Chem. C, 11, 3095-3100 (2023). - "Spontaneous Intercluster Electron Transfer X2– + X0 → 2 X– (X = PtAu24(SCnH2n+1)18) in Solution: Promotion by Long Alkyl Chains"
Megumi Suyama, Shinjiro Takano, and Tatsuya Tsukuda*
J. Am. Chem. Soc., 145, 3361-3368 (2023). - "Supervalence Bonding in Bi-icosahedral Cores of [M1Au37(SC2H4Ph)24]– (M = Pd and Pt): Fusion-Mediated Synthesis and Anion Photoelectron Spectroscopy"
Emi Ito, Shun Ito, Shinjiro Takano, Toshikazu Nakamura, and Tatsuya Tsukuda*
JACS Au, 2, 2627-2634 (2022). - "Synergistically Activated Pd Atom in Polymer-Stabilized Au23Pd1 Cluster"
Shingo Hasegawa, Shinya Masuda, Shinjiro Takano, Koji Harano, Jun Kikkawa, and Tatsuya Tsukuda*
ACS Nano, 16, 16932-16940 (2022). - "Doping-Mediated Energy-Level Engineering of M@Au12 Superatoms (M = Pd, Pt, Rh, Ir) for Efficient Photoluminescence and Photocatalysis"
Haru Hirai, Shinjiro Takano, Takuya Nakashima, Takeshi Iwasa, Tetsuya Taketsugu, and Tatsuya Tsukuda*
Angew. Chem., Int. Ed., 61, e202207290 (2022). - "Polymer-Stabilized Au38 Cluster: Atomically Precise Synthesis by Digestive Ripening and Characterization of the Atomic Structure and Oxidation Catalysis"
Shingo Hasegawa, Shinya Masuda, Shinjiro Takano, Koji Harano, and Tatsuya Tsukuda*
ACS Catal., 12, 6550-6558 (2022). - "N-Heterocyclic Carbene-Stabilized Hydrido Au24 Nanoclusters: Synthesis, Structure, and Electrocatalytic Reduction of CO2"
Viveka K. Kulkarni, Behnam Nourmohammadi Khiarak, Shinjiro Takano, Sami Malola, Emily L. Albright, Tetyana I. Levchenko, Mark D. Aloisio, Cao-Thang Dinh*, Tatsuya Tsukuda*, Hannu Häkkinen*, and Cathleen M. Crudden*
J. Am. Chem. Soc., 144, 9000-9006 (2022). - "NHC-Stabilized Au10 Nanoclusters and Their Conversion to Au25 Nanoclusters"
Paul A. Lummis, Kimberly M. Osten, Tetyana I. Levchenko, Maryam Sabooni Asre Hazer, Sami Malola, Bryan Owens-Baird, Alex J. Veinot, Emily L. Albright, Gabriele Schatte, Shinjiro Takano, Kirill Kovnir*, Kevin G. Stamplecoskie*, Tatsuya Tsukuda*, Hannu Häkkinen*, Masakazu Nambo*, and Cathleen M. Crudden*
JACS Au, 2, 875-885 (2022). - "Synthesis and Characterization of Enantiopure Chiral Bis NHC-Stabilized Edge-Shared Au10 Nanocluster with Unique Prolate Shape"
Renee W. Y. Man, Hong Yi, Sami Malola, Shinjiro Takano, Tatsuya Tsukuda*, Hannu Häkkinen*, Masakazu Nambo*, and Cathleen M. Crudden*
J. Am. Chem. Soc., 144, 2056-2061 (2022). - "Synthesis of active, robust and cationic Au25 cluster catalysts on double metal hydroxide by long-term oxidative aging of Au25(SR)18"
Shinya Masuda, Shinjiro Takano, Seiji Yamazoe and Tatsuya Tsukuda*
Nanoscale, 14, 3031-3039 (2022). - "A Face-to-Face Dimer of Au3 Superatoms Supported by Interlocked Tridentate Scaffolds Formed in Au18S2(SR)12"
Taro Shigeta, Shinjiro Takano, and Tatsuya Tsukuda*
Angew. Chem., Int. Ed., 61, e202113275 (2022). - "Decorating an Anisotropic Au13 Core with Dendron Thiolates: Enhancement of Optical Absorption and Photoluminescence"
Tsubasa Omoda, Shinjiro Takano, Shinya Masuda and Tatsuya Tsukuda*
Chem. Commun., 57, 12159 (2021). - "Critical Role of CF3 Groups in the Electronic Stabilization of [PdAu24(C≡CC6H3(CF3)2)18]2- as Revealed by Gas-Phase Anion Photoelectron Spectroscopy"
Shun Ito, Kiichirou Koyasu, Shinjiro Takano, and Tatsuya Tsukuda*
J. Phys. Chem. Lett., 12, 10417 (2021). - "Ligand Effects on the Hydrogen Evolution Reaction Catalyzed by Au13 and Pt@Au12: Alkynyl vs Thiolate"
Xiang Li, Shinjiro Takano, and Tatsuya Tsukuda*
J. Phys. Chem. C, 125, 23226-23230 (2021). - "Chemical Transformations of [MAu8(PPh3)8]2+ (M = Pt, Pd) and [Au9(PPh3)8]3+ in Methanol Induced by Irradiation of Atmospheric Pressure Plasma"
Sojiro Emori, Shinjiro Takano, Kiichirou Koyasu, and Tatsuya Tsukuda*
J. Chem. Phys., 155, 124312 (2021). - "Synergistic Effect in Ir- or Pt-Doped Ru Nanoparticles: Catalytic Hydrogenation of Carbonyl Compounds under Ambient Temperature and H2 Pressure"
Shotaro Matsuda, Shinya Masuda, Shinjiro Takano, Nobuyuki Ichikuni, and Tatsuya Tsukuda*
ACS Catal., 11, 10502-10507 (2021). - "Effects of π-Electron Systems on Optical Activity of Au11 Clusters Protected by Chiral Diphosphines"
Naoaki Shinjo, Shinjiro Takano, and Tatsuya Tsukuda*
Bull. Korean Chem. Soc., 42, 1265-1268 (2021). - "Photoluminescence of Doped Superatoms M@Au12 (M = Ru, Rh, Ir) Homoleptically Capped by (Ph2)PCH2P(Ph2): Efficient Room-Temperature Phosphorescence from Ru@Au12"
Shinjiro Takano, Haru Hirai, Takuya Nakashima, Takeshi Iwasa, Tetsuya Taketsugu, and Tatsuya Tsukuda*
J. Am. Chem. Soc., 143, 10560-10564 (2021). - "Atomically-Ordered Trimetallic Superatoms M@Au6Ag6 (M = Pd, Pt): Synthesis and Photoluminescence Properties"
Shinjiro Takano, and Tatsuya Tsukuda*
Chem. Lett., 50, 1419-1422 (2021). - "Ligand Effects on the Structures of [Au23L6(C≡CPh)9]2+ (L = N-Heterocyclic Carbene vs Phosphine) with Au17 Superatomic Cores"
Koto Hirano, Shinjiro Takano, and Tatsuya Tsukuda*
J. Phys. Chem. C, 125, 9930 (2021). - "New Magic Au24 Cluster Stabilized by PVP: Selective Formation, Atomic Structure, and Oxidation Catalysis"
Shingo Hasegawa, Shinjiro Takano, Koji Harano, and Tatsuya Tsukuda*
JACS Au, 1, 660 (2021). - "Few-nm-Sized, Phase-Pure Au5Sn Intermetallic Nanoparticles: Synthesis and Characterization"
Satoshi Osugi, Shinjiro Takano, Shinya Masuda, Koji Harano, and Tatsuya Tsukuda*
Dalton Trans., 50, 5177 (2021). - "Synergistic Effects of Pt and Cd Codoping to Icosahedral Au13 Superatoms"
Megumi Suyama, Shinjiro Takano, and Tatsuya Tsukuda*
J. Phys. Chem. C, 124, 23923 (2020). - "Controlled Dimerization and Bonding Scheme of Icosahedral M@Au12 (M = Pd, Pt) Superatoms"
Emi Ito, Shinjiro Takano*, Toshikazu Nakamura and Tatsuya Tsukuda*
Angew. Chem., Int. Ed., 60, 645 (2021). - "Collision-Induced Reductive Elimination of 1,3-Diynes from [MAu24(C≡CR)18]2– (M = Pd, Pt) Yielding Clusters of Superatoms"
Shun Ito, Kiichirou Koyasu, Shinjiro Takano, and Tatsuya Tsukuda*
J. Phys. Chem. C, 124, 19119 (2020). - "Electron-Rich Gold Clusters Stabilized by Polyvinylpyridines as Robust and Active Oxidation Catalysts"
Atsushi Matsuo, Shingo Hasegawa, Shinjiro Takano, and Tatsuya Tsukuda*
Langmuir, 36, 7844-7849 (2020). - Understanding Doping Effects on Electronic Structures of Gold Superatoms: A Case Study of Diphosphine-Protected M@Au12 (M = Au, Pt, Ir)"
Haru Hirai, Shinjiro Takano,Toshikazu Nakamura and Tatsuya Tsukuda*
Inorg. Chem., 59, 17889 (2020). - "Electron Microscopic Observation of an Icosahedral Au13 Core in Au25(SeR)18 and Reversible Isomerization between Icosahedral and Face-Centered Cubic Cores in Au144(SC2H4Ph)60"
Ryo Takahata, Seiji Yamazoe, Yosuke Maehara, Kenji Yamazaki, Shinjiro Takano, Wataru Kurashige, Yuichi Negishi, Kazutoshi Gohara and Tatsuya Tsukuda*
J. Phys. Chem. C, 124, 6907 (2020). - "Asymmetric Aerobic Oxidation of Secondary Alcohols Catalyzed by Poly(N-vinyl-2-pyrrolidone)-stabilized Gold Clusters Modified with Cyclodextrin Derivatives"
Koto Hirano, Shinjiro Takano, and Tatsuya Tsukuda*
Chem. Commun., 55, 15033-15036 (2019). - "Alkynyl-Protected Au22(C≡CR)18 Clusters Featuring New Interfacial Motifs and R-Dependent Photoluminescence"
Shun Ito, Shinjiro Takano, and Tatsuya Tsukuda*
J. Phys. Chem. Lett., 10, 6892-6896 (2019). - "Efficient and Selective Conversion of Phosphine-Protected (MAu8)2+ (M = Pd, Pt) Superatoms to Thiolate-Protected (MAu12)6+ or Alkynyl-Protected (MAu12)4+ Superatoms via Hydride Doping"
Shinjiro Takano*, Shun Ito, and Tatsuya Tsukuda*
J. Am. Chem. Soc., 141, 15994-16002 (2019). - "Robust, Highly Luminescent Au13 Superatoms Protected by N-Heterocyclic Carbenes"
Mina R. Narouz, Shinjiro Takano, Paul A. Lummis, Tetyana I. Levchenko, Ali Nazemi, Sami Kaappa, Sami Malola, Goonay Yousefalizadeh, Larry A. Calhoun, Kevin G. Stamplecoskie*, Hannu Häkkinen*, Tatsuya Tsukuda*, and Cathleen M. Crudden*
J. Am. Chem. Soc., 141, 14997-15002 (2019). - "Stoichiometric Formation of Open-Shell [PtAu24(SC2H4Ph)18]– via Spontaneous Electron Proportionation between [PtAu24(SC2H4Ph)18]2– and [PtAu24(SC2H4Ph)18]0"
Megumi Suyama, Shinjiro Takano, Toshikazu Nakamura and Tatsuya Tsukuda*
J. Am. Chem. Soc., 141, 14048-14051 (2019). - "Reduction-Resistant [Au25(cyclohexanethiolate)18]0 with an Icosahedral Au13 Core"
Tsubasa Omoda, Shinjiro Takano and Tatsuya Tsukuda*
Chem. Lett., 48, 885-887 (2019). - "N-heterocyclic carbene-functionalized magic-number gold nanoclusters"
Mina R. Narouz, Kimberly M. Osten, Phillip J. Unsworth, Renee W. Y. Man, Kirsi Salorinne, Shinjiro Takano, Ryohei Tomihara, Sami Kaappa, Sami Malola, Cao-Thang Dinh, J. Daniel Padmos, Kennedy Ayoo, Patrick J. Garrett, Masakazu Nambo, J. Hugh Horton, Edward H. Sargent, Hannu Häkkinen*, Tatsuya Tsukuda* and Cathleen M. Crudden*
Nature Chemistry, 11, 419-425 (2019). - "Synthesis of trimetallic (HPd@M2Au8)3+ superatoms (M = Ag, Cu) via hydride-mediated regioselective doping to (Pd@Au8)2+"
Haru Hirai, Shinjiro Takano, and Tatsuya Tsukuda*
ACS Omega, 4, 7070-7075 (2019). - "Interconversions of Structural Isomers of [PdAu8(PPh3)8]2+ and [Au9(PPh3)8]3+ Revealed by Ion Mobility Mass Spectrometry"
Keisuke Hirata, Papri Chakraborty, Abhijit Nag, Shinjiro Takano, Kiichirou Koyasu, Thalappil Pradeep* and Tatsuya Tsukuda*
J. Phys. Chem. C, 122, 23123-23128 (2018). - "Hydride-Mediated Controlled Growth of a Bimetallic (Pd@Au8)2+ Superatom to a Hydride-Doped (HPd@Au10)3+ Superatom"
Shinjiro Takano, Haru Hirai, Satoru Muramatsu, and Tatsuya Tsukuda*
J. Am. Chem. Soc., 140, 12314-12317 (2018). - "Hydride-Doped Gold Superatom (Au9H)2+: Synthesis, Structure and Transformation"
Shinjiro Takano, Haru Hirai, Satoru Muramatsu, and Tatsuya Tsukuda*
J. Am. Chem. Soc., 140, 8380-8383 (2018). - "An Au25(SR)18 Cluster with a Face-Centered Cubic Core"
Tsubasa Omoda, Shinjiro Takano, Seiji Yamazoe, Kiichirou Koyasu, Yuichi Negishi, and Tatsuya Tsukuda*
J. Phys. Chem. C, 122, 24, 13199-13204 (2018). - "Collision-Induced Dissociation of Undecagold Clusters Protected by Mixed Ligands [Au11(PPh3)8X2]+ (X = Cl, C ≡ CPh)"
Ryohei Tomihara, Keisuke Hirata, Hiroki Yamamoto, Shinjiro Takano, Kiichirou Koyasu, and Tatsuya Tsukuda*
ACS Omega, 3, 6, 6237-6242 (2018). - "Prominent hydrogenation catalysis of a PVP-stabilized Au34 superatom provided by doping a single Rh atom"
Shingo Hasegawa, Shinjiro Takano, Seiji Yamazoe, and Tatsuya Tsukuda*
Chem. Commun., 54, 5915-5918 (2018). - "Anion Photoelectron Spectroscopy of Free [Au25(SC12H25)18]−"
Keisuke Hirata, Kenshiro Yamashita, Satoru Muramatsu, Shinjiro Takano, Keijiro Ohshimo, Toshiyuki Azuma, Ryuzo Nakanishi, Takashi Nagata, Seiji Yamazoe, and Tatsuya Tsukuda*
Nanoscale, 9, 13409-13412 (2017). - "Metal Substitution Effect on a Three-Dimensional Cyanide-Bridged Fe Spin-Crossover Network"
Kenta Imoto, Shinjiro Takano, and Shin-ichi Ohkoshi*
Inorganics 5, 63 (2017). - "Suppressing Isomerization of Phosphine–Protected Au9 Cluster by Bond Stiffening Induced by Single Pd Atom Substitution"
Seiji Yamazoe, Shota Matsuo, Satoru Muramatsu, Shinjiro Takano, Kiyofumi Nitta, and Tatsuya Tsukuda*
Inorg. Chem. 56, 8319-8325 (2017). - "A Gold Superatom with 10 Electrons in Au13(PPh3)8(p-SC6H4CO2H)3"
Shinjiro Takano, Seiji Yamazoe, and Tatsuya Tsukuda*
APL. Mater. 5, 053402 (2017). - "Amplification of Optical Activity of Gold Clusters by the Proximity of BINAP"
Shinjiro Takano and Tatsuya Tsukuda*
J. Phys. Chem. Lett. 7, 4509-4513 (2016). - "Selective and High-Yield Synthesis of Oblate Superatom [PdAu8(PPh3)8]2+"
Shota Matsuo, Shinjiro Takano, Seiji Yamazoe, Kiichirou Koyasu, and Tatsuya Tsukuda*
ChemElectroChem 3, 1206 (2016). - "Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates"
Seiji Yamazoe, Shinjiro Takano, Wataru Kurashige, Toshihiko Yokoyama, Kiyofumi Nitta, Yuichi Negishi, and Tatsuya Tsukuda*
Nature Communications 7, 10414 (2016). - "Synthesis and Catalytic Application of Ag44 Clusters Supported on Mesoporous Carbon"
Masaru Urushizaki, Hirokazu Kitazawa, Shinjiro Takano, Ryo Takahata, Seiji Yamazoe, and Tatsuya Tsukuda*
J. Phys. Chem. C 119, 27483-27488 (2015). - "Slow-reduction synthesis of a thiolate-protected one-dimensional gold cluster showing an intense near-infrared absorption"
Shinjiro Takano, Seiji Yamazoe, Kiichirou Koyasu, and Tatsuya Tsukuda*
J. Am. Chem. Soc. 137, 7027-7030 (2015). - "A Critical Size for Emergence of Nonbulk Electronic and Geometric Structures in Dodecanethiolate-Protected Au Cluster"
Yuichi Negishi*, Tafu Nakazaki, Sami Malola, Shinjiro Takano, Yoshiki Niihori, Wataru Kurashige, Seiji Yamazoe, Tatsuya Tsukuda*, and Hannu Häkkinen*
J. Am. Chem. Soc. 137, 1206-1212 (2015). - "Binding motif of terminal alkynes on gold clusters"
Prasenjit Maity, Shinjiro Takano , Seiji Yamazoe, Tomonari Wakabayashi and Tatsuya Tsukuda
J. Am. Chem. Soc. 135, 9450-9457 (2013). - "90-degree optical switching of output second harmonic light in chiral photomagnet"
Shin-ichi Ohkoshi, Shinjiro Takano , Kenta Imoto, Marie Yoshikiyo, Asuka Namai and Hiroko Tokoro
Nature Photonics 8, 65 (2014). - "Light-induced spin-crossover magnet"
Shin-ichi Ohkoshi, Kenta Imoto, Yoshihide Tsunobuchi, Shinjiro Takano and Hiroko Tokoro
Nature Chemistry 3, 564 (2011).
学会発表
- "ジホスフィン保護18電子系超原子M@Au12 (M = Re, W): 合成と構造評価", 高野慎二郎, 佃達哉, 第17回分子科学討論会, 大阪大学豊中キャンパス, 大阪, 2023年9月
- "18電子系超原子Re@Au12の合成と評価", 高野慎二郎, 佃達哉, ナノ学会第20回大会, 近畿大学, オンライン, 2022年5月
- "Development of Efficient and Selective Transformation Reactions of Hydride-Doped Gold Superatoms", Shinjiro Takano, Tatsuya Tsukuda, Pacifichem2021, Online, Dec. 2021. (Poster)
- "効率的な室温リン光を示すジホスフィン保護Ru@Au12超原子の合成と評価", 高野慎二郎, 平井遥, 中嶋琢也, 岩佐豪, 武次徹也, 佃達哉, 第15回分子科学討論会, 北海道大学, オンライン, 2021年9月
- "Development of precise transformation reactions of gold superatoms initiated by hydride doping",Shinjiro Takano, Shun Ito, Tatsuya Tsukuda, 日本化学会第100回春季年会, 東京理科大学野田キャンパス, 千葉, 2020年3月
- "ヒドリドドープ金超原子を利用した精密表面変換反応の開発", 高野慎二郎, 伊藤駿, 佃達哉, 第13回分子科学討論会, 名古屋大学東山キャンパス, 愛知, 2019年9月
- "ヒドリドドーピングを鍵とする金超原子の精密変換反応の開拓:表面化学修飾", 高野慎二郎, 伊藤駿, 佃達哉, ナノ学会第17回大会, かごしま県民交流センター, 鹿児島, 2019年5月
- "ヒドリドドープ金超原子の合成と評価", 高野慎二郎, 平井遥, 村松悟, 佃達哉, 第12回分子科学討論会, 福岡国際会議場, 福岡, 2018年9月
- "ヒドリドドープされた金超原子の生成と評価", 高野慎二郎, 平井遥, 村松悟, 佃達哉, ナノ学会第16回大会, 東京大学, 東京, 2018年5月
- "吸着水素を利用した金クラスターの成長制御", 高野慎二郎, 平井遥, 佃達哉, 第11回分子科学討論会, 東北大学, 宮城, 2017年9月
- "王冠型6 電子系金超原子の核成長反応", 高野慎二郎, 佃達哉, ナノ学会第15回大会, 北海道立道民活動センターかでる2・7, 北海道, 2017年5月
- "キラルホスフィン保護金クラスターの合成とその光学特性", 高野慎二郎, 佃達哉, 第10回分子化学討論会, 神戸ファッションマート, 兵庫, 2016年9月
- "A thiolate-protected gold cluster with strong near-IR absorption band: Synthesis and chracterization", Shinjiro Takano, Seiji Yamazoe, Kiichirou Koyasu and Tatsuya Tsukuda, GOLD 2015, Cardiff, UK, July 2015. (Poster)
- "Synthesis of a thiolate-protected one-dimensional gold cluster showing an intense NIR absorption band", Shinjiro Takano, Seiji Yamazoe, Kiichirou Koyasu and Tatsuya Tsukuda, ISMPC 15, Yamanashi, Japan, July 2015. (Oral)
- "チオラート保護一次元構造金クラスターの合成と光学特性", 高野慎二郎, 山添誠司, 小安喜一郎, 佃達哉, ナノ学会第13回大会, 東北大学, 宮城, 2015年5月.
- "面心立方構造の量子サイズ金クラスター:精密合成と近赤外線吸収バンドの観測", 高野慎二郎, 山添誠司, 小安喜一郎, 佃達哉, 第8回分子科学討論会, 広島大学, 広島, 2014年9月.
- "Novel Thiolate-protected Gold Clusters with Sub-2 nm Sized and Fcc cores: Synthesis and optical Property", Shinjiro Takano, Seiji Yamazoe, Kiichirou Koyasu and Tatsuya Tsukuda, ISSPIC XVII, Fukuoka, Japan, Sept. 2014. (poster)
- "fcc 構造を持つ量子サイズ金クラスターの合成と評価", 高野慎二郎, 山添誠司, 小安喜一郎, 佃達哉, 日本化学会第94春季年会, 名古屋大学, 愛知, 2014年3月.
総説・著書・解説
- "露出サイトを持つ IrAu12 クラスター:精密合成とプログラム連結" 福本優斗・重田翼・平井遥・高野慎二郎・原野幸治・佃達哉
- "N-Heterocyclic Carbene-Stabilized Atomically Precise Metal Nanoclusters"
Emily L. Albright, Tetyana I. Levchenko, Viveka K. Kulkarni, Angus I. Sullivan, Joseph F. DeJesus, Sami Malola, Shinjiro Takano, Masakazu Nambo*, Kevin Stamplecoskie*, Hannu Häkkinen*, Tatsuya Tsukuda*, and Cathleen M. Crudden*
J. Am. Chem. Soc., 146, 5759-5780 (2024).
- "Bonding and Electronic Interactions of Hydrogen with Gold Superatoms"
Subarna Maity, Shinjiro Takano, Shinya Masuda, and Tatsuya Tsukuda*
J. Phys. Chem. C, 128, 19-30 (2024). - "強発光性合金クラスターの創出に向けて"
高野慎二郎
Bull. Jpn. Soc. Coord. Chem., 80, 49-53 (2022). - "配位子保護金クラスターの標的合成法の開拓と物性制御指針の探究"
高野慎二郎
Molecular Science, 16, A0121 (2022). - "化学修飾された金属超原子の化学"
高野慎二郎・佃達哉
フロンティアナノ金属錯体化学 (山下正廣, 小西克明編, 錯体化学会フロンティア選書, 三共出版, 2022) 108-132. - Chapter6: "Atomically Precise Synthesis of Chemically Modified Superatoms
Shinjiro Takano and Tatsuya Tsukuda
in Superatoms: Principles, Synthesis, and Applications, edited by Puru Jena and Qiang Sun
John Wiley & Sons, Hoboken (2022).
- "Chemically Modified Gold/Silver Superatoms as Artificial Elements at Nanoscale: Design Principles and Synthesis Challenges"
Shinjiro Takano, and Tatsuya Tsukuda*
J. Am. Chem. Soc., 143, 1683-1698 (2021). - "Ligand-Protected Gold/Silver Superatoms: Current Status and Emerging Trends"
Haru Hirai, Shun Ito, Shinjiro Takano, Kiichirou Koyasu and Tatsuya Tsukuda*
Chem. Sci., 11, 12233 (2020). - "Toward Controlling the Electronic Structures of Chemically Modified Superatoms of Gold and Silver"
Tsubasa Omoda, Shinjiro Takano, and Tatsuya Tsukuda*
Small, 17, 2001439 (2021). - "ヒドリドドーピングを鍵とする金超原子の精密変換反応の開拓:表面化学修飾" 高野慎二郎・伊藤駿・佃達哉
- "クラスター間の自発的電子移動による開殻系クラスター[PtAu24(SC2H4Ph)18]–の化学量論的生成" 陶山めぐみ・高野慎二郎・中村敏和・佃達哉
- "Hydride Doping of Chemically Modified Gold-Based Superatoms"
Shinjiro Takano, Shingo Hasegawa, Megumi Suyama, and Tatsuya Tsukuda*
Acc. Chem. Res., 51, 3074-3083 (2018). - "金超原子の化学 −ナノスケールの人工原子−" 高野慎二郎・佃達哉
- "Controlled Synthesis of Carbon Supported Gold Clusters for Rational Catalyst Design"
Seiji Yamazoe, Tatchamapan Yoskamtorn, Shinjiro Takano, Sudarat Yadnum, Jumras Limtrakul, and Tatsuya Tsukuda*
Chem. Rec., 16, 2338-2348 (2016). - Chapter2: "Controlled Synthesis: Size Control" Shinjiro Takano and Tatsuya Tsukuda
- "極細金ナノワイヤーの精密合成とその光学特性" 高野慎二郎・佃達哉
- "超原子と超原子分子: 金原子が つくるナノ構造体の美の世界" 高野慎二郎・佃達哉
ナノ学会会報, 23, 17-22 (2024).
ナノ学会会報, 18, 31-36 (2020).
ナノ学会会報, 18, 21-26 (2019).
現代化学, 553, 50-54 (2017).
in Protected Metal Clusters: From Fundamentals to Applications (1st Ed.), edited by Tatsuya Tsukuda and Hannu Häkkinen
Elsevier, Amsterdam (2015).
化学と工業, 68, 1028 (2015).
化学と教育, 62, 602-605 (2014).
依頼講演
- "配位子保護金クラスターの標的合成法の開拓と物性制御指針の探究", 第16回分子科学討論会2022横浜, 慶應義塾大学矢上キャンパス, 神奈川, 2022年9月
- "Targeted Synthesis of Ligand-Protected Gold Superatoms and Exploration of Their Design Principles", 日本化学会第102春季年会, オンライン, 2022年3月
- "Hydride-Doped Gold Clusters: Syntheses, Structures, and Transformations", The 76 th Fujihara Seminar
- "保護された金クラスター:合成とその性質", 分子集積化学特論4, 東京理科大学神楽坂キャンパス, 東京, 2019年1月
- "Ligand protected gold cluster:Synthesis and Optical Property", ETHZ-UTokyo Joint Symposium of Frontier Chemistry, Tokyo, Japan, Nov. 2016
- "金クラスターの化学:精密合成とその応用",錯体化学若手の会 関東支部勉強会, 東京理科大学神楽坂キャンパス, 東京, 2016年5月.
International Workshop on Designer Nanocluster Materials -From Gas Phase to Condensed Phase-, Grand Hotel New Oji, Tomakomai, Hokkaido, Japan, Sep. 2019
競争的資金等
- 基盤研究B, 科学研究費補助金, 2023-2026.
- 田中貴金属記念財団 貴金属に関わる研究助成金 奨励賞, 2022.
- 池谷科学技術振興財団 研究助成金, 2019-2020.
- 若手研究, 学術研究助成基金助成金, 2019-2021.
- 特別研究員奨励費, 科学研究費補助金, 2014-2016.