東京大学大学院理学系研究科化学専攻  無機化学研究室(西原研究室)

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お問合せ

〒113-0033
東京都文京区本郷7-3-1
Tel 03-5841-4346
Fax 03-5841-8063
nisihara@chem.s.u-tokyo.ac.jp

研究室メンバー

前田 啓明

前田 啓明
特任助教

生年月日

1987年9月2日

出身

富山県南砺市

学歴

平成18年  3月  富山県立高岡高等学校 卒業
平成22年  3月  東京大学理学部化学科 卒業
平成24年  3月  東京大学大学院理学系研究科化学専攻修士課程 修了
平成27年  3月  東京大学大学院理学系研究科化学専攻博士課程 修了

職歴

平成24年4月-平成27年3月 日本学術振興会特別研究員(DC1)
平成27年4月- 同年11月 東京大学大学院理学系研究科化学専攻 特任研究員
平成27年11月 - 東京大学大学院理学系研究科化学専攻 特任助教

受賞

2012年 錯体化学会第62回討論会学生講演賞

研究テーマ

逐次的錯体形性反応を用いた電極表面上への錯体ワイヤの構築および電気化学的評価
金属錯体ナノシートの創製

原著論文

  1. Xinsen Sun, Kuo-Hui Wu, Ryota Sakamoto, Tetsuro Kusamoto, Hiroaki Maeda, Hiroshi Nishihara
    "Conducting π-Conjugated Bis(iminothiolato)nickel Nanosheet"
    Chem. Lett., 2017, doi:10.1246/cl.170382. → link
  2. Takamasa Tsukamoto, Kenji Takada, Ryota Sakamoto, Ryota Matsuoka, Ryojun Toyoda, Hiroaki Maeda, Toshiki Yagi, Michihiro Nishikawa, Naoaki Shinjo, Shuntaro Amano, Tadashi Iokawa, Narutaka Ishibashi, Tsugumi Oi, Koshiro Kanayama, Rina Kinugawa, Yoichiro Koda, Toshiyuki Komura, Shuhei Nakajima, Ryota Fukuyama, Nobuyuki Fuse, Makoto Mizui, Masashi Miyasaki, Yutaro Yamashita, Kuni Yamada, Wenxuan Zhang, Ruocheng Han, Wenyu Liu, Taro Tsubomura, Hiroshi Nishihara
    "Coordination Nanosheets Based on Terpyridine-zinc(II) complexes: As Photoactive Host Materials"
    J. Am. Chem. Soc., 2017, 139, 5359-5366.→link
  3. Ryota Sakamoto, Toshiki Yagi, Ken Hoshiko, Shinpei Kusaka, Ryota Matsuoka, Hiroaki Maeda, Zheng Liu, Qian Liu, Wai-Yeung Wong, Hiroshi Nishihara
    "Photofunctionality in Porphyrin-Hybridized Bis(dipyrrinato)zinc(II) Complex Micro- and Nanosheets"
    Angew. Chem. Int. Ed., 2017, 56, 3526-3530.→link
  4. Yoshinori Yamanoi, Tetsuhiro Kobayashi, Hiroaki Maeda, Mariko Miyachi, Masato Ara, Hirokazu Tada, Hiroshi Nishihara
    "Effective Method for Micro-Patterning Arene-Terminated Monolayers on a Si(111) Electrode"
    Langmuir, 2016, 32, 6825-6829.→link
  5. Suzaliza Mustafar, Kuo-Hui Wu, Ryojun Toyoda, Kenji Takada, Hiroaki Maeda, Mariko Miyachi, Ryota Sakamoto, Hiroshi Nishihara
    "Electrochemical fabrication of one-dimensional porphyrinic wires on electrodes"
    Inorg. Chem. Front., 2016, 3, 370-375.→link
  6. Hiroaki Maeda, Ryota Sakamoto, Hiroshi Nishihara
    "Electron transport of bis(terpyridine)iron(II) complex wires on a semiconducting electrode"
    J. Electroanal. Chem., in press. (DOI:10.1016/j.jelechem.2016.04.027)→link
  7. Hiroaki Maeda, Ryota Sakamoto, Hiroshi Nishihara
    "Rapid Electron Transport Phenomenon in the Bis(terpyridine)metal Complex Wire: Marcus Theory and Electrochemical Impedance Spectroscopy Study"
    J. Phys. Chem. Lett., 2015, 6, 3821-3826.→link
  8. Aayushi Bajpayee, Hiraoki Maeda, Shunsuke Katagiri, Ryota Sakamoto, Hiroshi Nishihara
    "Bis(terpyridine)iron(II) Complex Wires with a Bithiophene Linker for Superior Long Range Electron Transport"
    Chem. Lett., 2015, 44, 1211-1213.→link
  9. Ryota Sakamoto, Shunsuke Katagiri, Hiroaki Maeda, Yoshihiko Nishimori, Seiji Miyashita, Hiroshi Nishihara
    "Electron Transport Dynamics in Redox-Molecule-Terminated Branched Oligomer Wires on Au(111)"
    J. Am. Chem. Soc., 2015, 137, 734-741.→link
  10. Hiroaki Maeda, Ryota Sakamoto, Hiroshi Nishihara
    "Surface Junction Effects on Interfacial Electron Transfer Between Bis(terpyridine)iron(II) and Hydrogen-Terminated Silicon(111) Electrode"
    Chem. Eur. J., 2014, 20, 2761-2764.→link
  11. Koji Yamamoto, Naohiro Oyamada, Sheng Xia, Yuta Kobayashi, Masahiko Yamaguchi, Hiroaki Maeda, Hiroshi Nishihara, Tadafumi Uchimaru, Eunsang Kwon
    "Equatorenes: Synthesis and Properties of Chiral Naphthalene, Phenanthrene, Chrysene, and Pyrene Possessing Bis(1-adamantyl) Groups at the Peri-Position"
    J. Am. Chem. Soc., 2013, 135, 16526-16532.→link
  12. Kuo-Hui Wu, Hiroaki Maeda, Tetsuya Kambe, Ken Hoshiko, Eunice Jia Han Phua, Ryota Sakamoto, Hiroshi Nishihara
    "A bis(terpyridine)iron network polymer on carbon for a potential energy storage material"
    Dalton Trans., 2013, 42, 15877-15880.→link
  13. Ryota Sakamoto, Yuuki Ohirabaru, Ryota Matsuoka, Hiroaki Maeda, Shunsuke Katagiri, Hiroshi Nishihara
    "Orthogonal bis(terpyridine)-Fe(II) metal complex wires on a tripod scaffold: Rapid electron transport"
    Chem. Commun., 2013, 49, 7108-7110.→link
  14. Ryota Sakamoto, Shunsuke Katagiri, Hiroaki Maeda, Hiroshi Nishihara
    "Triarylamine-Conjugated Bis(terpyridine)-Fe(II) Complex Wires: Rapid and Long-Range Electron Transport Ability"
    Chem. Lett., 2013, 42, 553-555.→link
  15. Shunsuke Katagiri, Ryota Sakamoto, Hiroaki Maeda, Yoshihiko Nishimori, Tomochika Kurita, Hiroshi Nishihara
    "Terminal Redox Site Effect on the Long-Range Electron Conduction of Fe(tpy)2 Oligomer Wires on Gold Electrode"
    Chem. Eur. J., 2013, 19, 5088-5096.→link
  16. Yoshinori Yamanoi, Junya Sendo, Tetsuhiro Kobayashi, Hiroaki Maeda, Yusuke Yabusaki, Mariko Miyachi, Ryota Sakamoto, Hiroshi Nishihara
    "A New Method to Generate Arene-Terminated Si(111) & Ge(111) Surfaces via a Palladium-Catalyzed Arylation Reaction"
    J. Am. Chem. Soc., 2012, 134, 20433-20439.→link
  17. Yoshihiko Nishimori, Hiroaki Maeda, Shunsuke Katagiri, Junya Sendo, Mariko Miyachi, Ryota Sakamoto, Yoshinori Yamanoi, Hiroshi Nishihara
    "Synthesis and Electron Transfer Properties of Metal Complex Oligomer Wires with an Inherent Potential Gradient on Gold Electrode"
    Macromol. Symp., 2012, 317-318, 276-285. →link
  18. Hiroaki Maeda, Ryota Sakamoto, Yoshihiko Nishimori, Junya Sendo, Fumiyuki Toshimitsu, Yoshinori Yamanoi, Hiroshi Nishihara
    "Bottom-up fabrication of redox-active metal complex oligomer wires on an H-terminated Si(111) surface"
    Chem. Commun., 2011, 47, 8644-8646. →link

総説

  1. Ryota Sakamoto, Kenji Takada, Tigmansu Pal, Hiroaki Maeda, Tetsuya Kambe, Hiroshi Nishihara
    "Coordination nanosheets (CONASHs): strategies, structures and functions"
    Chem. Commun., 2017, 53, 5781-5801. → link
  2. Hiroaki Maeda, Ryota Sakamoto, Hiroshi Nishihara
    "Interfacial Synthesis of Electrofunctional Coordination Nanowires and Nanosheets of Bis(terpyridine) Complexes"
    Coord. Chem. Rev., 2017, in press, DOI:10.1016/j.ccr.2017.02.013.→link
  3. Hiroaki Maeda, Ryota Sakamoto, Hiroshi Nishihara
    "Coordination Programming of Two-dimensional Metal Complex Frameworks"
    Langmuir, 2016, 32, 2527-2538.→link
  4. 田 健司、坂本 良太、前田 啓明、西原 寛
    「エレクトロニクス・スピントロニクスへ応用可能な「ボトムアップ型」配位ナノシート」
    化学工業, 2016, in press
  5. Ryota Sakamoto, Wu Kuo-Hui, Ryota Matsuoka, Hiroaki Maeda, Hiroshi Nishihara
    "π-Conjugated bis(terpyridine)metal complex molecular wires"
    Chem. Soc. Rev., 2015, 25, 7698-7714. →link
  6. Ryota Sakamoto, Shunsuke Katagiri, Hiroaki Maeda, Hiroshi Nishihara
    "Bis(terpyridine) metal complex wires: Excellent long-range electron transfer ability and controllable intrawire redox conduction on silicon electrode"
    Coord. Chem. Rev., 2013, 257, 1493-1506. →link
  7. Hiroaki Maeda, Ryota Sakamoto, Hiroshi Nishihara
    "Metal Complex Oligomer and Polymer Wires on Electrodes: Tactical Constructions and Versatile Functionalities"
    Polymer, 2013, 54, 4383-4403.→link
  8. 前田 啓明、坂本 良太、西原 寛
    「錯体分子ワイヤの電気化学評価とその長距離電子移動能」
    表面科学, 2011, 32,641-646.→link

著書

  1. 公益社団法人日本化学会 編著
    「CSJ Current Review 二次元物質の科学 グラフェンなどの分子シートが生み出す新世界」
    株式会社東京化学同人、2017年、Chap.19を共著
  2. 西原 寛、市村 彰男、田中 晃二 編著
    「錯体化学選書9 金属錯体の電子移動と電気化学」
    三共出版株式会社、2013年、4章4節を共著

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