List of Recent Publication

Original Papers

2010

  1. "Insertion of Platinum and Palladium into a Sulfur(IV)-Sulfur(II) Bond of a Sulfur-substituted Sulfurane"
    N. Kano, S. Kusaka, and T. Kawashima, Dalton Trans., 39, 456-460 (2010).
  2. "Synthesis of a C3 Symmetric Host Molecule for C60 Bearing a Bicyclic Triarylphosphate Framework"
    J. Kobayashi, Y. Domoto, and T. Kawashima, Chem. Lett., in press.

2009

  1. "Umpolung of a Hydrogen Atom of Water by Using a Hexacoordinated Phosphate and Its Application to Deuteride Reduction Reactions of Carbonyl Compounds"
    H. Miyake, N. Kano, and T. Kawashima, J. Am. Chem. Soc., 131, 16622-16623 (2009).
  2. "Fluorescence Properties of Simple N-Substituted Aldimines with a B−N Interaction and Their Fluorescence Quenching by a Cyanide Ion"
    J. Yoshino, N. Kano, and T. Kawashima, J. Org. Chem., 74, 7496-7503 (2009).
  3. "Development of a Sila-Friedel-Crafts Reaction and Its Application to the Synthesis of Dibenzosilole Derivatives"
    S. Furukawa, J. Kobayashi, and T. Kawashima, J. Am. Chem. Soc., 131, 14192-14193 (2009).
  4. "Inclusion of C60 into the Hexagonal Columnar Space Formed by Intra- and Intermolecular CH⋅⋅⋅π Interactions"
    J. Kobayashi, Y. Domoto, and T. Kawashima, Chem. Commun., 2009, 6186-6188.
  5. "Multi-step Detection of Cyanide Ion by a Bis(dimesitylboryl)dibenzoazaborine"
    T. Agou, M. Sekine, J. Kobayashi, and T. Kawashima, J. Organomet. Chem., 694, 3833-3836 (2009).
  6. "Synthesis of π-Conjugated Dendrimers Based on Azaborines"
    T. Agou, T. Kojima, J. Kobayashi, and T. Kawashima, Org. Lett., 11, 3534-3537 (2009).
  7. "Synthesis and Reversible Control of the Fluorescent Properties of a Divalent Tin-Dipyrromethene"
    J. Kobayashi, T. Kushida, and T. Kawashima, J. Am. Chem. Soc., 131, 10836-10837 (2009).
  8. "Formation of a 2-Amino-4H-3,1-benzoxathiin from a Tetracoordinated 1,2-Thiazetidine via the Aza-Pummerer Type Rearrangement"
    N. Kano, Y. Daicho, T. Kawashima, J. Sulf. Chem., 30, 245-249 (2009).
  9. "Synthesis, Structure, and Reactivity of Pentacoordinate Hydrosilanes Bearing a 2-(Phenylazo)phenyl Group"
    M. Yamamura, N. Kano, and T. Kawashima, Z. Anorg. Allg. Chem., 635,1295-1299 (2009).
  10. "Synthesis of Dibenzochalcogenaborins and Systematic Comparisons of Their Optical Properties by Changing a Bridging Chalcogen Atom"
    J. Kobayashi, K. Kato, T. Agou, and T. Kawashima, Chem. Asian J., 4, 42-49 (2009).
  11. "Synthesis and Reactivity of a Bis(dimesitylboryl)azaborine and Its Fluoride Sensing Ability"
    T. Agou, M. Sekine, J. Kobayashi, and T. Kawashima, Chem. Commun., 2009, 1894-1896.
  12. "Detection of Biologically Important Anions in Aqueous Media by Dicationic Azaborines Bearing Ammonio or Phosphonio Groups"
    T. Agou, M. Sekine, J. Kobayashi, T. Kawashima, Chem. Eur. J., 15, 5056-5062 (2009).
  13. "Perfectly "Anti-Apicophilic" Phosphoranes: Conversion of a 1-Hydro-5-carbaphosphatrane into 1-Alkyl- and 1-Aryl-5-carbaphosphatranes"
    J. Kobayashi and T. Kawashima, Phosphorus, Sulfur, Silicon Relat. Elem., 184, 1028-1035 (2009).
  14. "Enhancement of the Lewis Acidity by Substitution of Sulfur-containing Hetero Aromatics in Triarylboranes"
    S. Miyasaka, J. Kobayashi, and T. Kawashima, Tetrahedron Lett., 50, 3467-3469 (2009).

2008

  1. "Structure and Properties of a Sulfur(IV)−Sulfur(II)-Bond Compound: Reversible Conversion of a Sulfur-Substituted Organosulfurane into a Thiol"
    N. Kano, Y. Itoh, Y. Watanabe, S. Kusaka, and T. Kawashima, Angew. Chem. Int. Ed., 47, 9430-9433 (2008).
  2. "A Novel Ylide-stabilized Carbene; Formation and Electron Donating Ability of Amino(sulfur-ylide)carbene"
    J. Kobayashi, S.-y. Nakafuji, A. Yatabe, and T. Kawashima, Chem. Commun., 2008, 6233-6235.
  3. "Crucial Role of N･･･Si Interactions in th e Solid State Coloration of Disilylazobenzenes"
    M. Yamamura, N. Kano, T. Kawashima, T. Matsumoto, J. Harada, and K. Ogawa, J. Org. Chem., 73, 8244-8249 (2008).
  4. "Quenching and Recovery of Fluorescence of Azobenzenes by Acid-base Reactions"
    J. Yoshino, N. Kano, and T. Kawashima, Chem. Lett., 37, 960-961 (2008).
  5. "Synthesis of organoboron compounds bearing an azo group and substituent effects on their structures and photoisomerization"
    J. Yoshino, N. Kano, and T. Kawashima, Tetrahedron, 64, 7774-7781 (2008).
  6. "Generation and Coordination Properties of a Carbene Bearing a Phosphorus Ylide : An Intensely Electron-Donating Carbene"
    S.-y. Nakafuji, J. Kobayashi, and T. Kawashima, Angew. Chem. Int. Ed., 47, 1141-1144 (2008).
  7. "Chemistry of Carbaphosphatranes"
    T. Kawashima, Phosphorus, Sulfur, Silicon Relat. Elem., 183, 306-312 (2008).
  8. "Synthesis, Optical Properties, and Reactivities of A Dibenzophosphaborin and Its Derivatives"
    J. Kobayashi, T. Agou and T. Kawashima, Phosphorus, Sulfur, Silicon Relat. Elem., 183, 389-392 (2008).
  9. "Synthesis and Complexations of a Novel Stable Carbene Bearing a Phosphorus Ylide"
    S.-y. Nakafuji, J. Kobayashi, and T. Kawashima, Phosphorus, Sulfur, Silicon Relat. Elem., 183, 642-643 (2008).
  10. "Synthesis and Properties of Pentacoordinate Phosphorus Compounds Containing a Pentacoordinate Silicon Atom"
    M. Miyake, N. Kano, and T. Kawashima, Phosphorus, Sulfur, Silicon Relat. Elem., 183, 673-674 (2008).

2007

  1. "Hypervalent Silicon and Phosphorus Atoms in Single Molecules: Synthesis and Properties of Phosphoranylalkoxysilicates and a Phosphoranyloxysilicate", N. Kano, H. Miyake, and T. Kawashima, Chem. Lett., 36, 1260-1261 (2007).
  2. "Study on the Electronic Effect on Coordinating Donors in Heptacoordinate Trichlorogermanes"
    K. Iwanaga, J. Kobayashi, and T. Kawashima, Tetrahedron, 63, 10127-10132 (2007).
  3. "Steric Stabilization of a Monomeric Proalumatrane: Experimental and Theoretical Studies"
    W. Su, J. Kobayashi, A. Ellern, T. Kawashima, and J. G. Verkade, Inorg. Chem., 46, 7953-7959 (2007).
  4. "Development of a General Route to Periphery-Functionalized Azaborines and Ladder-Type Azaborines by Using Common Intermediates",
    T. Agou, J. Kobayashi, and T. Kawashima, Chem. Commun., 2007, 3204-3206.
  5. "Electronic and Optical Properties of Ladder-Type Heteraborins",
    T. Agou, J. Kobayashi, and T. Kawashima, Chem. Eur. J., 13, 8051-8060 (2007).
  6. "Phase Transfer of Fluoride Ion by Phosphonioborins",
    T. Agou, J. Kobayashi, Y. Kim, F. P. Gabbaï, and T. Kawashima, Chem. Lett., 36, 976-977 (2007).
  7. "Intramolecular Allylation of the Azo Group of 2-(Allylsilyl)azobenzenes and Its Photocontrol"
    M. Yamamura, N. Kano, and T. Kawashima, J. Organomet. Chem., 692, 313-325 (2007).
  8. "Synthesis of the Most Intensely Fluorescent Azobenzene by Utilizing the B-N Interaction"
    J. Yoshino, N. Kano, and T. Kawashima, Chem. Commun., 2007, 559-561. (Inside Front Cover Page)
  9. "Fluoride Ion Complexation by a Cationic Borane in Aqueous Solution"
    M. H. Lee, T. Agou, J. Kobayashi, T. Kawashima, and F. P. Gabbaï, Chem. Commun., 2007, 1133-1135
  10. "Photoswitching of the Reactivity Involving Hydrosilylation of a 1,1,3,3-Tetrahydrodisiloxane Bearing Two Azo Groups"
    M. Yamamura, N. Kano, and T. Kawashima, Tetrahedron Lett., 48, 4033-4036 (2007).
  11. " Syntheses and Characterization of Alkylzirconium Complexes Containing Two Silanolato Ligands with a Bowl-shaped Framework "
    I. Shimo, K. Goto, and T. Kawashima, J. Organomet. Chem., 692 , 2115-2119 (2007).
  12. "Synthesis and Crystal Structure of a Zirconium Complex Containing Germanolato Ligands and Its Catalytic Activity for Ethylene Polymerization"
    K. Goto, I. Shimo, T. Okumura, and T. Kawashima, Chem. Lett., 36, 776-777 (2007).

2006

  1. "Syntheses, Structures, and Thermolyses of Pentacoordinate 1,2-Oxastibetanes: Potential Intermediates in the Reactions of Stibonium Ylides with Carbonyl Compounds"
    Y. Uchiyama, N. Kano, and T. Kawashima, J. Org. Chem., 71, 659-670 (2006).
  2. "Shuttlecock-like Arrangement of a Tweezer-type Cavitand in the Crystalline State"
    A. Yoshida, K. Goto, and T. Kawashima, Bull. Chem. Soc. Jpn., 79, 793-795 (2006).
  3. "Reactivity of 1-Hydro-5-carbaphosphatrane Based on Tautomerization between Pentavalent Phosphorane and Trivalent Cyclic Phosphonite"
    J. Kobayashi, K. Goto, T. Kawashima, M. W. Schmidt, and S. Nagase, Chem. Eur. J., 12, 3811-3820 (2006).
  4. "Reversible Photoswitching of the Coordination Numbers of Silicon in Organosilicon Compounds Bearing a 2-(Phenylazo)phenyl Group"
    N. Kano, F. Komatsu, M. Yamamura, and T. Kawashima, J. Am. Chem. Soc., 128, 7097-7109 (2006).
  5. "Syntheses, Structure, and Optical Properties of Ladder-Type Fused Azaborines"
    T. Agou, J. Kobayashi, and T. Kawashima, Org. Lett., 8, 2241-2244 (2006).
  6. "Pentacoordinate 1H-Phosphirenes: Reactivity, Bonding Properties, and Substituent Effect on Their Structures and Thermal Stability"
    S. Sase, N. Kano, and T. Kawashima, J. Org. Chem., 71, 5448-5456 (2006).
  7. "Systematic Study on the Structures and Reactivities of Hydrazobenzenes and Azobenzenes Bearing a Chalcogenophosphoryl Group"
    M. Yamamura, N. Kano, and T. Kawashima, Inorg. Chem., 45, 6497-6507 (2006).
  8. "Syntheses, Structures, and Reactions of Heptacoordinate Trihalogermanes Bearing a Triarylmethyl-Type Tetradentate Ligand"
    K. Iwanaga, J. Kobayashi, T. Kawashima, N. Takagi, and S. Nagase, Organometallics, 25, 3388-3396 (2006).
  9. "Formation of a Stable Sulfenic Acid by Hydrolysis of a Thionitrate and a Sulfenyl Bromide"
    K. Goto, K. Shimada, S. Furukawa, S. Miyasaka, Y. Takahashi, and T. Kawashima, Chem. Lett., 35, 862-863 (2006).
  10. "A Potential Intermediate for the Aza-Corey-Chaykovsky Reaction: Synthesis, Structure, and Thermolysis of a Pentacoordinate 1,2-Thiazetidine 1-Oxide"
    N. Kano, Y. Daicho, and T. Kawashima, Org. Lett., 8, 4625-4627 (2006).
  11. "Tuning of the Optical Properties and Lewis Acidity of Dibenzopnictogenaborins by Modification on Bridging Main Group Elements"
    T. Agou, J. Kobayashi, and T. Kawashima, Inorg. Chem., 45, 9137-9144 (2006).

2005

  1. "Dithiocarboxylic Acid Salts of Group 1-17 Elements (Except for Carbon)"
    N. Kano and T. Kawashima, Top. Curr. Chem., 251, 141-180 (2005).
  2. "Synthesis, Structures, and Properties of Quinone-Bridged Calix[6]arenes"
    S. Akine, K. Goto, and T. Kawashima, Bull. Chem. Soc. Jpn., 78, 169-179 (2005).
  3. "Thermolysis and Photolysis of Stable Se-Nitrososelenols"
    K. Shimada, K. Goto, and T. Kawashima, Chem. Lett., 34, 654-655 (2005).
  4. "Syntheses of the First Se-Nitrososelenol and Related Compounds"
    K. Goto, K. Shimada, and T. Kawashima, Phosphorus, Sulfur Silicon Relat. Elem., 180, 945-949 (2005).
  5. "Fixation of Both O2 and CO2 from Air by a Crystalline Palladium Complex Bearing N-Heterocyclic Carbene Ligands"
    M. Yamashita, K. Goto, and T. Kawashima, J. Am. Chem. Soc., 127, 7294-7295 (2005).
  6. "Theoretical Evidence for Enhanced NO Dimerization in Aromatic Hosts: Implications for the Role of the Electrophile (NO)2 in Nitric Oxide Chemistry"
    Y.-L. Zhao, M. D. Bartberger, K. Goto, K. Shimada, T. Kawashima, and K. N. Houk, J. Am. Chem. Soc., 127, 7964-7965 (2005).
  7. "Disilanes Containing Two High Coordinate Silicon Atoms Bridged by Carboxylate Ligands: Synthesis, Structure, and Dynamic Behavior"
    N. Kano, N. Nakagawa, Y. Shinozaki, T. Kawashima, Y. Sato, Y. Naruse, and S. Inagaki, Organometallics, 24, 2823-2826 (2005).
  8. "Syntheses and Structures of Bowl-shaped Triarylphosphines and Their Palladium(II) Complexes"
    Y. Ohzu, K. Goto, H. Sato, and T. Kawashima, J. Organomet. Chem., 690, 4175-4183 (2005).
  9. "Photoswitching of the Lewis Acidity of a Catecholborane Bearing an Azo Group Based on the Change in Coordination Number of Boron"
    N. Kano, J. Yoshino, and T. Kawashima, Org. Lett., 7, 3909-3911 (2005).
  10. "Thermal and Photocontrol of the Equilibrium between a 2-Phosphinoazobenzene and an Inner Phosphonium Salt"
    M. Yamamura, N. Kano, and T. Kawashima, J. Am. Chem. Soc., 127, 11954-11955 (2005).
  11. "Solvent-Dependent Crystallization of 1-Hydro-6-carbaphosphatrane and Its Tautomer"
    S. Nakafuji, J. Kobayashi, T. Kawashima, and M. W. Schmidt, Inorg. Chem., 44, 6500-6502 (2005).
  12. "Dibenzophosphaborin: A Hetero-π-conjugated Molecule with Fluorescent Properties Based on Intramolecular Charge Transfer between Phosphorus and Boron Atoms"
    T. Agou, J. Kobayashi, and T. Kawashima, Org. Lett., 7, 4373-4376 (2005).
  13. "New Aspects in the Chemistry of Three-Membered Ring Compounds Containing a Highly Coordinate Main Group Element"
    T. Kawashima, Chin. J. Chem., 23, 1267-1269 (2005).
  14. "Nanoscale Molecular Cavities for Stabilization of Highly Reactive Species"
    K. Goto and T. Kawashima, J. Synth. Org. Chem., Jpn., 63, 1157-1170 (2005) (Special Issue in English).

2004

  1. "Water-Coordinated Neutral Silane Complex: A Frozen Intermediate of Hydrolysis of Alkoxysilanes"
    J. Kobayashi, K. Kawaguchi, and T. Kawashima, J. Am. Chem. Soc., 126, 16318-16319 (2004).
  2. "Isolation of a Se-Nitrososelenol: A New Class of Reactive Nitrogen Species Relevant to Protein Se-Nitrosation"
    K. Shimada, K. Goto, T. Kawashima, N. Takagi, Y.-K. Choe, and S. Nagase, J. Am. Chem. Soc., 126, 13238-13239 (2004).
  3. "Preparation of an Aliphatic-substituted Hypervalent Iodine Compound―Tetracoordinate 1,2-Iodoxetane 1-Oxide, and Its Application to Oxidation"
    N. Kano, M. Ohashi, K. Hoshiba, and T. Kawashima, Tetrahedron Lett., 45, 8173-8175 (2004).
  4. "Isolation of a Cyclic Intermediate in the Reaction of a Phosphorus Ylide with Elemental Sulfur: Synthesis, Structure, and Reactivity of a 1,2σ5-Thiaphosphirane"
    S. Sase, N. Kano, and T. Kawashima, Chem. Lett., 33, 1434-1435 (2004).
  5. "Synthesis, Structure, and Reactivity of a Symmetrically Substituted 9-Phosphatriptycene Oxide and Its Derivatives"
    T. Agou, J. Kobayashi, and T. Kawashima, Heteroat. Chem., 15, 437-446 (2004).
  6. "Evaluation of σ-Donating Ability of a 9-Phosphatriptycene and Its Application to Catalytic Reactions"
    T. Agou, J. Kobayashi, and T. Kawashima, Chem. Lett., 33, 1028-1029 (2004).
  7. "Reactivity Control of an Allylsilane Bearing a 2-(Phenylazo)phenyl Group by Photoswitching of the Coordination Number of Silicon"
    N. Kano, M. Yamamura, and T. Kawashima, J. Am. Chem. Soc., 126, 6250-6251 (2004).
  8. "Synthesis, Structure, and Thermolysis of Pentacoordinate 1,2-Oxastibetanes"
    T. Kawashima, Y. Uchiyama, and N. Kano, Phosphorus, Sulfur, Silicon Relat. Elem., 179, 849-852 (2004).
  9. "Synthesis and Structure of a Novel Symmetrically Substituted Phosphatriptycene Oxide"
    J. Kobayashi, T. Agou, and T. Kawashima, Phosphorus, Sulfur, Silicon Relat. Elem., 179, 959-960 (2004).

2003

  1. "Synthesis, Structure, and Thermolysis of a Pentacoordinate 1,2-Oxastibetane"
    Y. Uchiyama, N. Kano, and T. Kawashima, J. Am. Chem. Soc., 125, 13346-13347 (2003).
  2. "Synthesis, Crystal Structure, and Photoreaction of a Disiloxane Bearing Two 2-(Phenylazo)phenyl Groups"
    N. Kano, M. Yamamura, F. Komatsu, and T. Kawashima, J. Organomet. Chem., 686, 192-197 (2003).
  3. "A Bowl-Shaped Triarylphosphane with a Large Cone Angle: Synthesis and Crystallographic Analysis of a [(PdX2)3(PR3)2]-Type Complex"
    Y. Ohzu, K. Goto, and T. Kawashima, Angew. Chem. Int. Ed., 42, 5714-5717 (2003).
  4. "Synthesis and Structural Characterization of a Novel Bowl-type Germanol and Its Derivatives"
    K. Goto, I. Shimo, and T. Kawashima, Bull. Chem. Soc. Jpn., 76, 2389-2394 (2003).
  5. "A Novel and Convenient Synthetic Route to Phosphatriptycene and Systematic Comparisons of Phosphatriptycene Derivatives"
    J. Kobayashi, T. Agou, and T. Kawashima, Chem. Lett., 32, 1144-1145 (2003).
  6. "Reaction of Stable Sulfenic and Selenenic Acids Containing a Bowl-type Steric Protection Group with a Phosphine: The First Elucidation of the Mechanism of Reduction of Sulfenic and Selenenic Acids"
    K. Goto, K. Shimada, M. Nagahama, R. Okazaki, and T. Kawashima, Chem. Lett., 32, 1080-1081 (2003).
  7. "Synthesis and Crystal Structure of a Novel Heterocyclic Compound Bearing a Pentacoordinate Germanium Atom and a Deprotonated HMPA Moiety"
    N. Kano, S. Goto, and T. Kawashima, Organometallics, 22, 1152-1155 (2003).
  8. "Syntheses, Structures, and Thermolyses of Three- and Four-Membered Heterocyclic Compounds Containing Highly Coordinate Main Group Elements"
    T. Kawashima, Bull. Chem. Soc. Jpn., 76, 471-483 (2003).
  9. "Four-membered Heterocyclic Compounds Containing High Coordinate Group 16 Elements"
    T. Kawashima, Coord. Chem. Rev., 244, 137-147 (2003).
  10. "Isolation and Structural Analysis of Novel Conformational Isomers of the m-Xylylene-bridged Calix[6]arenes: the "Partial Cone" and "Inverted Cone" Isomers"
    S. Akine, K. Goto, and T. Kawashima, Tetrahedron Lett., 44, 1171-1174 (2003).

2002

  1. "Synthesis and Structure of the First 1,2σ5-Selenaphosphirane"
    S. Sase, N. Kano, and T. Kawashima, J. Am. Chem. Soc., 124, 9706-9707 (2002).
  2. "Synthesis, Structure, and Bonding Porperties of 5-Carbaphosphatranes: A New Class of Main Group Atrane"
    J. Kobayashi, K. Goto, T. Kawashima, M. W. Schmidt, and S. Nagase, J. Am. Chem. Soc., 124, 3703-3712 (2002).
  3. "Hypercoordination to a Saturated Carbon Atom"
    Y. Naruse, S. Inagaki, N. Kano, N. Nakagawa, and T. Kawashima, Tetrahedron Lett., 43, 5759-5762 (2002).
  4. "Synthesis, Structure, and Thermolysis of a Novel Spirotellurane Bearing Two 1,2-Oxatelluretane Rings, 1,5-Dioxa-4λ4-telluraspiro[3.3]heptane: Oxirane and Olefin Formation Reactions"
    N. Kano, T. Takahashi, and T. Kawashima, Tetrahedron Lett., 43, 6775-6778 (2002).
  5. "Fluoride Ion Abstraction of Phosphonium Cations from Their Counter Anion: A Novel Synthetic Method of Fluorophosphoranes"
    S. Sase, N. Kano, and T. Kawashima, Chem. Lett., 2002, 268-269.
  6. "Synthesis and Structure of the First Pentacoordinate Thiasiliranide"
    K. Naganuma and T. Kawashima, J. Organomet. Chem., 643, 504-507 (2002).
  7. "Reactions of 1-Hydro-5-carbaphosphatrane: Tautomerization between Five Coordinate and Three Coordinate Species"
    J. Kobayashi, K. Goto, and T. Kawashima, Phosphorus, Sulfur, Silicon Relat. Elem., 177, 1405-1407 (2002).
  8. "Synthesis of Four- and Five-membered Heterocycles Derived from an Iminophosphorane"
    N. Kano, J.-H. Xing, A. Kikuchi, S. Kawa, and T. Kawashima, Phosphorus, Sulfur, Silicon Relat. Elem., 177, 1685-1687 (2002).
  9. "Bonding Properties of 5-Carbaphosphatranes"
    K. Goto, J. Kobayashi, T. Kawashima, M. W. Schmidt, and S. Nagase, Phosphorus, Sulfur, Silicon Relat. Elem., 177, 2037-2038 (2002).
  10. "Synthesis of the First Stable Pentacoordinate Selenaphosphirane"
    S. Sase, N. Kano, and T. Kawashima, Phosphorus, Sulfur, Silicon Relat. Elem., 177, 2039-2040 (2002).
  11. "Novel Synthetic Method of Fluorophosphoranes by Fluoride Ion Abstraction from Tetrafluoroborate"
    S. Sase, N. Kano, and T. Kawashima, Phosphorus, Sulfur, Silicon Relat. Elem., 177, 2041 (2002).
  12. "Synthesis of Novel Triarylphosphines Bearing a m-Terphenyl-based Dendrimer-type Framework"
    K. Goto, Y. Ohzu, H. Sato, and T. Kawashima, Phosphorus, Sulfur, Silicon Relat. Elem., 177, 2179 (2002).
  13. "Cycloaddition Reaction of an Iminophosphorane Bearing the Martin Ligand with Some Double-Bond Compounds: Syntheses, Structures and Thermolyses of a 1,3,2λ5-oxazaphosphetidine and a 1,3,2λ5-Diazaphosphetidine-4-thione"
    N. Kano, J.-H. Xing, S. Kawa, and T. Kawashima, Polyhedron, 21, 657-665 (2002).
  14. "Synthesis of a Heptacoordinate Trichlorosilane with a Tetradentate Ligand and Unusual Stability for Nucleophilic Substitution"
    J. Kobayashi, K. Ishida, and T. Kawashima, Silicon Chem., 1, 351-354 (2002).

2001

  1. "Reversible Photo-control of the Coordination Number of Silicon in a Tetrafluorosilicate Bearing a 2-(Phenylazo)phenyl Group"
    N. Kano, F. Komatsu, and T. Kawashima, J. Am. Chem. Soc., 123, 10778 (2001).
  2. "Synthesis, Structure, and Reactions of a Tricoordinate 1,2-Iodoxetane"
    T. Kawashima, K. Hoshiba, and N. Kano, J. Am. Chem. Soc., 123, 1507 (2001).
  3. "A Disilane Containing Two Heptacoordinate Silicon Atoms and Dithiocarboxylate Ligands"
    N. Kano, N. Nakagawa, and T. Kawashima, Angew. Chem. Int. Ed., 40, 3450 (2001).
  4. "Synthesis and Thermolysis of Novel Spiroselenuranes Bearing Two Oxaselenetane Rings: Double Oxirane Formation Reactions from 1,5-Dioxa-4λ4-selenaspiro[3.3]heptanes"
    F. Ohno, T. Kawashima, and R. Okazaki, Chem. Commun., 2001, 463.
  5. "Synthesis and Structure of a Novel Ladder-type Organobismuth Compound with Bismuth-Oxygen Interactions"
    Y. Uchiyama, N. Kano, and T. Kawashima, Organometallics, 20, 2440 (2001).
  6. "Synthesis, Crystal Structure and Thermolysis of the First Tetracoordinate 1λ4,2-Selenazetidines: Aziridine Formation Reaction from a Four-Membered Heterocycle Bearing Highly Coordinate Selenium"
    N. Kano, Y. Daicho, N. Nakanishi, and T. Kawashima, Org. Lett., 3, 691 (2001).
  7. "The First Isolable Pentacoordinate 1,2λ5-Azaphosphetine: Synthesis, X-ray Crystallograpic Analysis, and Dynamic Behaviour"
    N. Kano, A. Kikuchi, and T. Kawashima, Chem. Commun.,2001, 2096.
  8. "Novel Ring System with an Se-O-N Linkage: Synthesis and Crystal Structure of the First 1,2λ4,5-Oxaselenazolidine"
    N. Kano, N. Nakanishi, Y. Daicho, and T. Kawashima, Chem. Lett., 2001, 610.
  9. "Synthesis and Structure of 5-Carbaphosphatrane"
    J. Kobayashi, K. Goto, and T. Kawashima, Phosphorus, Sulfur, and Silicon, 168, 597 (2001).
  10. "Conformational Mobility of the Bridged Calix[6]arenes with Allyl and Ethyl Groups at the Lower Rim"
    S. Akine, K. Goto, and T. Kawashima, Bull. Chem. Soc. Jpn., 74, 2167 (2001).
  11. "The First Direct Oxidative Conversion of a Selenol to a Stable Selenenic Acid: Experimental Demonstration of Three Processes Included in the Catalytic Cycle of Glutathione Peroxidase"
    K. Goto, M. Nagahama, T. Mizushima, K. Shimada, T. Kawashima, and R. Okazaki, Org. Lett., 2001, 3569.
  12. "Synthesis, Structure, and Reactions of the First Stable Aromatic S-Nitrosothiol Bearing a Novel Dendrimer-type Steric Protection Group"
    K. Goto, Y. Hino, Y. Takahashi, T. Kawashima, G. Yamamoto, N. Takagi, and S. Nagase, Chem. Lett., 2001, 1204.
  13. "Synthesis, Structure, and Reactions of a Novel Triarylsilanol with a Bowl-type Framework: A Silanol Extremely Resistant to Self-condensation"
    K. Goto, T. Okumura, and T. Kawashima, Chem. Lett., 2001, 1258.
  14. "5-Carbaphosphatranes: The First Main Group Atrane Bearing a 1-5 Covalent Bond"
    J. Kobayashi, K. Goto, and T. Kawashima, J. Am. Chem. Soc., 123, 3387 (2001).
  15. "Synthesis and Reactions of Conformational Isomers of a Stable Selenenic Acid Bearing a Bridged Calix[6]arene Framework"
    K. Goto, T. Saiki, S. Akine, T. Kawashima, and R. Okazaki, Heteroatom Chem., 12, 195 (2001).
  16. "Structural Characterization of a Pentacooridante Monohydrosilane with the Apical Si-H Bond"
    K. Saruhashi, K. Goto, and T. Kawashima, Chem. Heterocycl. Compd. 2001, 1524.
  17. "Synthesis and Structures of Azobenzenes Bearing Silyl, Germyl, and Stannyl Groups at 2-Position"
    N. Kano, F. Komatsu, and T. Kawashima, Chem. Lett., 2001, 338.
  18. "Formation and X-ray Crystallographic Analysis of a 1,2λ5-Oxaphosphol-5(2H)-one"
    N. Kano, J.-H. Xing, A. Kikuchi, T. Kawashima, Heteroatom Chem., 12, 282 (2001).
  19. "Unusual Products in Reactions Using Ethyldimesitylborane, Mesityllithium, and Carbonyl Compounds"
    T. Kawashima, N. Yamashita, T. Kannabe, and R. Okazaki, Heteroatom Chem., 12, 354 (2001).
  20. "Synthesis and Structure of a Tricoordinate 1,2-Iodoxetane"
    T. Kawashima, K. Hoshiba, and N. Kano, Phosphorus, Sulfur, Silicon Relat. Elem., 168-169, 141 (2001).
  21. "Synthesis and Thermolysis of the Novel Ring Systems Containing Nitrogen and Tetracoordinate Selenium"
    N. Kano, Y. Daicho, N. Nakanishi, and T. Kawashima, Phosphorus, Sulfur, Silicon Relat. Elem., 168-169, 259 (2001).

2000

  1. "Small Ring Compounds Containing Highly Coordinate Group 14 Elements", T. Kawashima, J. Organomet. Chem., 611, 256 (2000).
  2. "Synthesis and Crystal Structure of a Stable S-Nitrosothiol Bearing a Novel Steric Protection Group and of the Corresponding S-Nitrothiol", K. Goto, Y. Hino, T. Kawashima, M. Kaminaga, E. Yano, G. Yamamoto, N. Takagi, and S. Nagase, Tetrahedron Lett., 41, 8479 (2000).
  3. "Synthesis, Structure, and Thermolysis of Pentacoordinate 1,3,2λ5-Oxazaphosphetidines: The Intermediates of Aza-Wittig Reactions", N. Kano, X. J. Hua, S. Kawa, and T. Kawashima, Tetrahedron Lett., 41, 5237 (2000).
  4. "Synthesis, Structure, and Redox Properties of a Quinone-Bridged Calix[6]arene", S. Akine, K. Goto, and T. Kawashima, Tetrahedron Lett., 41, 897 (2000).
  5. "Crystal Structures and Solvate Formation of Two Conformationally Frozen Isomers of a Bridged Calix[6]arene", S. Akine, K. Goto, and T. Kawashima, J. Inclusion Phenomena and Macrocyclic Chem., 36, 117 (2000).
  6. Structural Elucidation of 1,3-Phenylenebis(methylene)-bridged Calix[6]arenes with Four Uncapped Hydroxy Groupsﾓ, T. Saiki, S. Akine, K. Goto, N. Tokitoh, T. Kawashima, and R. Okazaki, Bull. Chem. Soc. Jpn.,73, 1893 (2000).

1999

  1. "Formation of a 1,3,2,4-Dioxadiborinanide, a Novel Boron-containing Heterocycle by Hydrolysis of a Tetracoordinate 1,2-Oxaboretanide and Its Crystal Structure", T. Kawashima, T. Kannabe, and R. Okazaki, Organometallics, 18, 5180 (1999).
  2. "Control Factors of Two Reaction Modes of Pentacoordinate 1,2-Oxasiletanides, the Peterson Reaction and Homo-Brook Rearrangement", K. Naganuma, T. Kawashima, and R. Okazaki, Chem. Lett., 1999, 1139.
  3. "Definition and Design of Diagonalization Reactions: Reactions of 1,2-Heteraazetidine N-Oxides", S. Inagaki, H. Ikeda, and T. Kawashima, Tetrahedron Lett., 40, 8893 (1999).
  4. "Different Aggregating Properties of Two Conformationally Frozen Isomers of a Water-Soluble Bridged Calix[6]arene", S. Akine, K. Goto, T. Kawashima, and R. Okazaki, Bull. Chem. Soc. Jpn., 72, 2781 (1999).
  5. "Gauche Conformers Relatively Stabilized by the Hypercoordination", S. Inagaki, S. Ohashi, and T. Kawashima, Org. Lett., 1, 1145 (1999).
  6. "Formation of a Borylene by Photolysis of an Overcrowded Bis(methylseleno)borane", M. Ito, N. Tokitoh, T. Kawashima, and R. Okazaki, Tetrahedron Lett., 40, 5557 (1999).
  7. "Desilylation-triggered Isomeriation of a Molecular Capsule from an Open-type to a Collapsed-type Isomer", S. Watanabe, K. Goto, T. Kawashima, and R. Okazaki, Tetrahedron Lett., 40, 3569 (1999).
  8. "Synthesis of the First Stable Pentacoordinate 1,2-Thiaphosphetene", T. Kawashima, T. Iijima, H. Kikuchi, and R. Okazaki, Phosphorus, Sulfur Silicon Relat. Elem., 144-146, 149 (1999).

1998

  1. "Synthesis of Tetracoordinate 1,2-Oxaselenetanes and Their Oxirane Formation Reaction", T. Kawashima, F. Ohno, and R Okazaki, Phosphorus, Sulfur Silicon Relat. Elem., 136-138, 501 (1998).
  2. "Stable Telluroketones: Synthesis and Characterization", M. Minoura, T. Kawashima, N. Tokitoh, and R. Okazaki, Phosphorus, Sulfur Silicon Relat. Elem., 136-138, 549 (1998).
  3. "Novel Synthetic Route to Stable Pentacoordinate 1,2-Oxaphosphetanes and Mechanism of Their Thermolysis, the Second Step of the Wittig Reaction (correction)", T. Kawashima, K. Kato, and R. Okazaki, J. Am. Chem. Soc., 120, 6848 (1998).
  4. "Generation and Decomposition of a Pentacoordinate Spirobis[1,2-oxasiletanide]", T. Kawashima, K. Naganuma, and R. Okazaki, Organometallics, 17, 367 (1998).
  5. "The Olefin Synthesis from β-Hydroxyalkylphosphonates Induced by Fluorides or Relatively Weak Bases", T. Kawashima, T. Ishii, N. Inamoto, N. Tokitoh, and R. Okazaki, Bull. Chem. Soc. Jpn., 71, 209 (1998).

1997

  1. "Synthesis and Double Olefin Extrusion of 2,2,6,6-Tetraaryl-1,5-dioxa-4λ5-phosphaspiro[3.3]heptanes", T. Kawashima, R. Okazaki, and R. Okazaki, Phosphorus, Sulfur Silicon Relat. Elem., 124-125, 379 (1997).
  2. "Formation of a Pentacoordinate 1,2-Oxastannetanide by Novel Base-Induced Rearrangement of a Bis(β-hydroxyalkyl)stannane", K. Naganuma, T. Kawashima, and R. Okazaki, Phosphorus, Sulfur Silicon Relat. Elem., 124-125, 513 (1997).
  3. "Synthesis, Structure, and Double Olefin Extrusion of All Three Diastereomers of 2,2,6,6-Tetrakis(4-chlorophenyl)-3,7-dimethyl-4-phenyl-1,5-dioxa-4λ5-phosphaspiro[3.3]heptane", T. Kawashima, R. Okazaki, and R. Okazaki, Angew. Chem., Int. Ed. Engl., 36, 2500 (1997).
  4. "Novel Reactivity of Tetracoordinate 1,2λ4-Oxaselenetanes: Oxirane Formation Reaction with Retention of Configuration", F. Ohno, T. Kawashima, and R. Okazaki, Chem. Commun., 1997, 1671.
  5. "Δ3-1,3,4-Telluradiazolines, a Novel Tellurium Containing Heterocycles: One-pot Synthesis, Structure, and Reactivity", M. Minoura, T. Kawashima, N. Tokitoh, and R. Okazaki, Tetrahedron, 53, 8137 (1997).
  6. "An Endohedral Simple Enol: The First Isolation of a β-Unsubstituted Simple Enol Utilizing a Lantern-Shaped Molecular Framework", S. Watanabe, K. Goto, T. Kawashima, and R. Okazaki, J. Am. Chem. Soc., 119, 3195 (1997).
  7. "The First Isolation of a Telluroketone and Its Reversible Dimerization", M. Minoura, T. Kawashima, and R. Okazaki, Tetrahedron Lett., 38, 2501 (1997).
  8. "Synthesis and Thermolysis of Hexacoordinate 1,2-Oxaphosphetanides", T. Kawashima, K. Watanabe, and R. Okazaki, Tetrahedron Lett., 38, 551 (1997).
  9. "Tandem Peterson-Michael Reaction Using α-Silylalkylphosphine Chalcogenides and Horner-Emmons Reaction of In Situ Generated α-Carbanions of Its Products", T. Kawashima, M. Nakamura, and N. Inamoto, Heterocycles, 44, 487 (1997).

1996

  1. "Experimental and Theoretical Evidence for Oxirane Formation Reaction of Pentacoordinate 1,2λ6-Oxathietanes with Retention of Configuration", T. Kawashima, F. Ohno, R. Okazaki, H. Ikeda, and S. Inagaki, J. Am. Chem. Soc., 118, 12455 (1996).
  2. "Synthesis, Stereochemistry, and Thermolysis of β-Aminoalkylboranes", T. Kawashima, N. Yamashita, and R. Okazaki, Chem. Lett., 1996, 213.
  3. "Synthesis, Structure, and Thermolysis of N-Apical 1,2λ5-Azaphosphetidines with a Pentacoordinate P Center and the First Observation of Their N-Equatorial Pseudorotamers", T. Kawashima, T. Soda, and R. Okazaki, Angew. Chem., Int. Ed. Engl., 35, 1096 (1996).
  4. "Syntheses, Structures, and Thermolyses of Four-Membered Heterocycles Containing a Highly Coordinate Main Group Element", T. Kawashima, K. Kato, N. Iwama, F. Ohno, H. Takami, N. Yamashita, Y. Nishiwaki, T. Soda, and R. Okazaki, Zhurn. Org. Khim., 32, 305 (1996).
  5. 「Wittig反応，Peterson反応および関連する反応中間体の合成と構造」、川島隆幸、有機合成化学協会誌, 54, 696 (1996).
  6. "Synthesis and Reactions of the Intermediates of the Wittig, Peterson, and Their Related Reactions", T. Kawashima and R. Okazaki, Synlett., 1996, 600.
  7. "Synthesis, Crystal Structure, and Thermolysis of a Pentacoordinate 1,2λ6-Oxathietane: An Intermediate of the Corey-Chaykovsky of Oxosulfonium Ylides?", F. Ohno, T. Kawashima, and R. Okazaki, J. Am. Chem. Soc., 118, 697 (1996).
  8. "Cycloaddition and Oxidation of a Stable Thioaldehyde: (2,4,6-Tri-t-butyl)thiobenzaldehyde", S. Watanabe, T. Yamamoto, T. Kawashima, and R. Okazaki, Bull. Chem. Soc. Jpn., 69, 719 (1996).
  9. "Weak Coordination of a Telluroketone in a η1-Mode Complex: Synthesis and Characterization of Pentacarbonyl(1,1,3,3-tetramethylindan-tellone)tungsten", M. Minoura, T. Kawashima, N. Tokitoh, and R. Okazaki, Chem. Commun., 1996, 123.
  10. "Synthesis and Thermolysis of Pentacoordinate 1,2-Azaphosphetidines", T. Kawashima, T. Soda, K. Kato, and R. Okazaki, Phosphorus, Sulfur Silicon Relat. Elem., 109-110, 489 (1996).

Others

  1. 狩野直和，川島隆幸
    「典型元素の配位数の光制御：典型元素置換基を有するアゾベンゼンの性質と応用」
    TCIメール, 136, 2-13 (2007).
  2. 川島隆幸
    「史上最高の蛍光量子収率を示すアゾベンゼンを合成」
    科研費NEWS, 1, 6 (2007).

Books

  1. "Product class 18: pentacoordinated phosphoranes"
    T. Kawashima and J. Kobayashi, in "Science of Synthesis",
    ed by F. Mathey, Georg Thieme Verlag KG, Stuttogart, New York, 42, 953-975 (2009).
  2. "Four Membered Rings with One Phosphorus, Arsenic, Antimony, or Bismuth Atom"
    J. Kobayashi and T. Kawashima, in "Comprehensive Heterocyclic Chemistry III",
    ed by A. R. Katritzky, C. A. Ramsden, E. F. V. Scriven, and R. J. K. Taylor, Elsevier Press, Oxford (2008), Vol. 2, Chap. 2.10, p. 479-509.
  3. 「アゾベンゼン系色素」
    狩野直和, 川島隆幸（分担執筆）, 「色材・顔料・色素の設計と開発」, 情報機構(2008), p. 281-288
  4. 「第５版実験化学講座 23」
    川島隆幸，小林潤司（分担執筆），日本化学会編，丸善 (2005)，p. 122-133.
  5. "Dithiocarboxylic Acid Salts of Group 1-17 Elements (Except for Carbon)"
    N. Kano and T. Kawashima, in "Topics in Current Chemistry"
    ed by S. Kato, Springer-Verlag, Heidelberg, 251, 141-180 (2005).
  6. "The Peterson and Related Reactions"
    N. Kano and T. Kawashima, in "Modern Carbonyl Olefination"
    ed by T. Takeda, Wiley-VCH, New York, Chap. 2, p. 18-103 (2004).
  7. 「21世紀の有機ケイ素化学　−機能性物質科学の宝庫−」
    狩野直和、川島隆幸、玉尾皓平編，シーエムシー出版，p. 47-53 (2004).
  8. "Synthesis of Hypervalent Organophosphorus Compounds and Their Reactions"
    T. Kawashima, in "Chemistry of Hypervalent Compounds"
    ed by K.-y. Akiba, Wiley-VCH, New York (1999), Chap. 6, p. 171-210.
  9. "Dihetracyclobutanes Containing Highly Coordinate Main Group Elements: Syntheses, Structures, and Thermolyses"
    T. Kawashima and R. Okazaki, in "Advances in Strained and Interesting Organic Molecules"
    ed by B. Halton, JAI Press Inc., Stamford (1999), p. 1-41.
  10. 「超原子価をもつ有機ケイ素およびリン化合物の合成と化学的挙動」
    川島隆幸、「季刊化学総説34　有機超原子価化合物」、日本化学会編, 丸善 (1998), p. 57-77.
  11. "Four Membered Rings with One Phosphorus, Arsenic, Antimony, or Bismuth Atom"
    T. Kawashima and R. Okazaki, in "Comprehensive Heterocyclic Chemistry II",
    ed by A. R. Katritzky, C. W. Rees, and E. F. V. Scriven, Pergamon Press, Oxford (1996), Vol. 1, Chap. 1.27, p. 833-866.
  12. 「大学院入試のための　解説有機化学総合演習」、川島隆幸、広川書店(1996), 兼松顕, 奥山格編集（分担執筆）