Publication List of Laurean ILIES
Original Publications:
41. “Indole Synthesis via Cyclative Formation of 2,3-Dizincioindoles and Regioselective Electrophilic Trapping”, L. Ilies, M. Isomura, S. Yamauchi, T. Nakamura, E. Nakamura, J. Am. Chem. Soc., 139, 23–26 (2017).
40. “Iron/Zinc-Cocatalyzed Directed Arylation and Alkenylation of C(sp3)-H Bonds with Organoborates”, L. Ilies, Y. Itabashi, R. Shang, E. Nakamura, ACS Catal., 7, 89–92 (2017).
39. “Iron-catalyzed ortho C-H Methylation of Aromatics Bearing a Simple Carbonyl Group with Methylaluminum and Tridentate Phosphine Ligand”, R. Shang, L. Ilies, E. Nakamura, J. Am. Chem. Soc., 138, 10132-10135 (2016).
38. “Oxidative C-H Activation Approach to Pyridone and Isoquinolone via Iron-Catalyzed Coupling of Amide with Alkyne”, T. Matsubara, L. Ilies, and E. Nakamura, Chem. Asian. J., DOI: 10.1002/asia.201501095. (invited contribution to “Catalysis and Transformation of Complex Molecules” special issue)
37. “Iron-Catalyzed Directed C(sp2)-H and C(sp3)-H Functionalization with Trimethylaluminum”, R. Shang, L. Ilies, E. Nakamura, J. Am. Chem. Soc., 137, 7660-7663 (2015). (Chosen as Synfact of the Month)
36. “Iron-Catalyzed Directed Alkylation of Alkenes and Arenes with Alkylzinc Halides”, Ilies, L.; Ichikawa, S.; Asako, S.; Matsubara, T.; Nakamura, E. Adv. Synth. Catal., 2015,357, 2175-2179. (Very Important Publication, invited contribution to the special issue dedicated to Stephen L. Buchwald)
35. “Iron-catalyzed C(sp2)–H Bond Functionalization with Organoboron Compounds”, Shang, R.; Ilies, L.; Asako, S.; Nakamura, E. J. Am. Chem. Soc. 2014, 136, 14349–14352. [highlighted in SYNFACTS, 2015, 969, and chosen Synfact of the Month].
34. “Iron-Catalyzed Directed Alkylation of Aromatic and Olefinic Carboxamides with Primary and Secondary Alkyl Tosylates, Mesylates, and Halides”, Ilies, L.; Matsubara, T.; Ichikawa, S.; Asako, S.; Nakamura, E. J. Am. Chem. Soc. 2014, 136, 13126–13129.
33. “ortho-Allylation of 1-Arylpyrazoles with Allyl Phenyl Ether via Iron-catalyzed C-H Bond Activation under Mild Conditions”, Asako, S.; Norinder, J.; Ilies, L.; Yoshikai, N.; Nakamura, E. Adv. Synth. Catal.2014, 356, 1481–1485. [invited contribution to the Directed C-H Activation thematic issue, Ed. J.-Q. Yu]
32. “Theoretical Study on Alkoxydiphosphine Ligand for Bimetallic Cooperation in Nickel-Catalyzed Monosubstitution of C–F Bond”, Asako, S.; Ilies, L.; Verma, P.; Ichikawa, S.; Nakamura, E. Chem. Lett. 2014, 43, 726–728.
31. “Synthesis of Polysubstituted Enynes via Iron-Catalyzed Carbomagnesiation of Conjugated Diynes”, Ilies, L.; Yoshida, T.; Nakamura, E. Synlett 2014, 25, 527–530.
30. “Synthesis of Anthranilic Acid Derivatives through Iron-Catalyzed Ortho Amination of Aromatic Carboxamides with N-Chloroamines”, Matsubara, T.; Asako, S.; Ilies, L.; Nakamura, E. J. Am. Chem. Soc. 2014, 136, 646–649 [SYNFACTS, 2014, 408].
29. “Iron-Catalyzed Ortho Allylation of Aromatic Carboxamides with Allyl Ethers”, Asako, S.; Ilies, L.; Nakamura, E. J. Am. Chem. Soc. 2013, 135, 17755–17757 [SYNFACTS, 2014, 190].
28. “beta-Arylation of Carboxamides via Iron-Catalyzed C(sp3)–H Bond Activation”, Shang, R.; Ilies, L.; Matsumoto, A.; Nakamura, E. J. Am. Chem. Soc. 2013, 135, 6030–6032 [SYNFACTS, 2013, 771].
27. "Iron-Catalyzed Allylic Arylation of Olefins via C(sp3)–H Activation under Mild Conditions", Sekine, M.; Ilies, L.; Nakamura, E. Org. Lett. 2013, 15, 714–717 [SYNFACTS, 2013, 433].
26. “Nickel-Catalyzed Synthesis of Diarylamines via Oxidatively Induced C–N Bond Formation at Room Temperature”, Ilies, L.; Matsubara T.; Nakamura, E. Org. Lett. 2012, 14, 5570–6673.
25. “Iron-Catalyzed Chemo- and Stereoselective Hydromagnesiation of Diarylalkynes and Diynes”, Ilies, L.; Yoshida, T.; Nakamura, E. J. Am. Chem. Soc. 2012, 134, 16951–16954 [SYNFACTS, 2013, 88].
24. “Synthesis of Polysubstituted Naphthalenes by Iron-Catalyzed [2 + 2 + 2] Annulation of Grignard Reagents with Alkynes”, Ilies, L.; Matsumoto, A.; Kobayashi, M.; Yoshikai, N.; Nakamura, E. Synlett 2012, 23, 2381–2384.
23. “Iron-Catalyzed ortho Monoarylation of Benzamide Derivatives", Ilies, L.; Konno, E.; Chen, Q.; Nakamura E. Asian J. Org. Chem 2012, 1,142–145.
22. “Nickel-Catalyzed Monosubstitution of Polyfluoroarenes with Organozinc Reagents Using Alkoxydiphosphine Ligand”, Nakamura Y.; Yoshikai, N.; Ilies, L.; Nakamura E. Org. Lett. 2012, 14, 3316–3319 [SYNFACTS, 2012, 1007].
21. "Iron-Catalyzed Regio- and Stereoselective Chlorosulfonylation of Terminal Alkynes with Aromatic Sulfonyl Chlorides", Zeng, X.; Ilies, L.; Nakamura, E. Org. Lett. 2012, 14, 954–956.
20. "Iron-Catalyzed Directed Coupling of Arene and Aryl Bromides Mediated by Metallic Magnesium", Ilies, L.; Kobayashi, M.; Matsumoto, A.; Yoshikai, N.; Nakamura, E. Adv. Synth. Catal. 2012, 354, 593–596.
19. "Synthesis of Functionalized 1H-Indenes via Copper-Catalyzed Arylative Cyclization of Arylalkynes with Aromatic Sulfonyl Chlorides", Zeng, X.; Ilies, L.; Nakamura, E. J. Am. Chem. Soc. 2011, 133, 17638–17640.
18. "Iron-Catalyzed Oxidative Monoarylation of Primary Amines with Organozinc Reagents", Nakamura, Y.; Ilies, L.; Nakamura, E. Org. Lett. 2011, 13, 5998–6001 [SYNFACTS, 2012, 199].
17. "Iron-Catalyzed C–H Bond Activation for the ortho-Arylation of Aryl Pyridines and Imines with Grignard Reagents", Yoshikai, N.; Asako, S.; Yamakawa, T.; Ilies, L.; Nakamura, E. Chem. Asian J., 2011, 6, 3059–3065.
16. "Cobalt-Catalyzed Coupling of Alkyl Grignard Reagent with Benzamide and 2-Phenylpyridine Derivatives through Directed C–H Bond Activation under Air", Chen, Q.; Ilies, L.; Yoshikai N.; Nakamura, E. Org. Lett. 2011, 13, 3232–3234. [SYNFACTS, 2011, 1008]
15. "Iron-Catalyzed Stereospecific Activation of Olefinic C–H Bonds with Grignard Reagent for Synthesis of Substituted Olefins", Ilies, L.; Asako, S.; Nakamura, E. J. Am. Chem. Soc. 2011, 133, 7672–7675. [SYNFACTS, 2011, 896]
14. "Phenanthrene Synthesis by Iron-Catalyzed [4 + 2] Benzannulation between Alkyne and Biaryl or 2-Alkenylphenyl Grignard Reagent", Matsumoto, A.; Ilies, L.; Nakamura, E. J. Am. Chem. Soc. 2011, 133, 6557–6559. [SYNFACTS 2011, 774]
13. "Cobalt-Catalyzed Chemoselective Insertion of Alkene into the Ortho C−H Bond of Benzamide", Ilies, L.; Chen, Q.; Zeng, X.; Nakamura, E. J. Am. Chem. Soc. 2011, 133, 5221–5223.
12. "Cobalt-Catalyzed ortho-Alkylation of Secondary Benzamide with Alkyl Chloride through Directed C–H Bond Activation", Chen, Q.; Ilies, L.; Nakamura, E. J. Am. Chem. Soc. 2011, 133, 428–429. [SYNFACTS 2011, 433]
11. "Synthesis of Tetrasubstituted Alkenes by Stereo- and Regioselective Stannyllithiation of Diarylacetylenes", Tsuji, H.; Ueda, Y.; Ilies, L.; Nakamura E. J. Am. Chem. Soc. 2010, 132, 11854–11855. [SYNFACTS 2010, 1257, also selected "SYNFACT of the month"]
10. "Iron-Catalyzed, Directed Oxidative Arylation of Olefins with Organozinc and Grignard Reagents", Ilies, L.; Okabe, J.;Yoshikai, N.; Nakamura, E. Org. Lett. 2010, 12, 2838–2840. [SYNFACTS 2010, 1053]
9. "Modular Synthesis of Polybenzo[b]silole Compounds for Hole-Blocking Material in Phosphorescent Organic Light Emitting Diodes", Ilies, L.; Sato, Y.; Mitsui, C.; Tsuji, H.; Nakamura, E. Chem. Asian J. 2010, 5, 1376–1381.
8. "Iron-Catalyzed C-C Bond Formation at α-Position of Aliphatic Amines via C-H Bond Activation through 1,5-Hydrogen Transfer", Yoshikai, N.; Mieczkowski, A.; Matsumoto, A.; Ilies, L.; Nakamura, E. J. Am. Chem. Soc. 2010, 132 , 5568–5569. [SYNFACTS 2010, 820]
7. "Synthesis of Benzo[b]siloles via KH-Promoted Cyclization of (2-Alkynylphenyl)silanes", Ilies, L.; Tsuji, H.; Nakamura, E. Org. Lett. 2009, 11, 3966–3968.
6. "Tetraaryl-substituted Benzo[1,2-b:4,5-b']dipyrroles: Synthesis, Properties, and Applications to Hole-injection Materials in OLED Devices”, Tsuji, H.; Yokoi, Y.; Mitsui, C.; Ilies, L.; Sato, Y.; Nakamura, E. Chem. Asian J. 2009, 4, 655–657.
5. "Modular Synthesis of Benzo[b]phosphole Derivatives via BuLi-Mediated Cyclization of (o-Alkynylphenyl)phosphine", Tsuji, H.; Sato, K.; Ilies, L.; Itoh, Y.; Sato, Y.; Nakamura, E. Org. Lett. 2008, 10, 2263–2265.
4. "Modular Synthesis of Functionalized Benzosiloles by Tin-Mediated Cyclization of (o-Alkynylphenyl)silane", Ilies, L.; Tsuji, H.; Sato, Y.; Nakamura, E. J. Am. Chem. Soc. 2008, 130, 4240–4241. [SYNFACTS 2008, 702]
3. "Synthesis and Properties of 2,3,6,7-Tetraarylbenzo[1,2-b:4,5-b']difurans as Hole-Transporting Material", Tsuji, H.; Mitsui, C.; Ilies, L.; Sato, Y.; Nakamura, E. J. Am. Chem. Soc. 2007, 129, 11902–11903.
2. "2,3-Disubstituted Benzofuran and Indole by Copper-Mediated C-C Bond Extension Reaction of 3-Zinciobenzoheterole", Nakamura, M.; Ilies, L.; Otsubo, S.; Nakamura, E. Org. Lett. 2006, 8, 2803–2805. [SYNFACTS 2006, 832]
1. "3-Zinciobenzofuran and 3-Zincioindole: Versatile Tools for Construction of Conjugated Structures Containing Multiple Benzoheterole Units", Nakamura, M.; Ilies, L.; Otsubo, S.; Nakamura, E. Angew. Chem., Int. Ed. 2006, 45, 944–947. [SYNFACTS 2006, 427]
Books, Reviews:
6. “Iron-Catalyzed C–H Bond Activation”, Ilies, L.; Nakamura, E. in Topics in Organometallic Chemistry: C-H Bond Activation and Catalytic Functionalization II, Eds.: P. H. Dixneuf and H. Doucet, pp 1-18, Springer Berlin Heidelberg (2016).
5. “Synthetic Strategy for Multisubstituted Fused Furan Compounds Using Main-Group Metal Reagents”, Tsuji, H.; Ilies, L.; Nakamura, E. Synlett 2006, 25, 2099–2110.
4. “Iron-Catalyzed Cross-Coupling Reactions”, Ilies, L.; Nakamura, E. in “The Chemistry of Organoiron Compounds”, pp 539-567 (Eds.: Ilan Marek and Zvi Rappoport), John Wiley & Sons, Ltd.: Chichester, UK 2014.
3. “Iron-Catalyzed Cross-Coupling Reactions”, Nakamura, E.; Hatakeyama, T.; Ito, S.; Ishizuka, K.; Ilies, L.; Nakamura, M. "Organic Reactions, vol. 83, Chapter 1 (Ed. Scott. E. Denmark), John Wiley & Sons, Inc. 2014.
2.「鉄触媒反応」イリエシュ ラウレアン・中村栄一，「鉄辞典」，朝倉書店 2014年; pp 234–241.
1.「鉄を触媒とする不活性炭素ｰ水素結合の直接官能基化」，イリエシュ ラウレアン・中村栄一，月刊ファインケミカル (特集：鉄触媒) 2012, 41, 40–45.