Publications, Koji Harano

Publication List of Koji HARANO

Original publications :

49. SHROOM3, The Gene Associated with Chronic Kidney Diseases, Affects The Podocyte Structure, R. Matsuura, A. Hiraishi, L. Holzman, H. Hanayama, K. Harano, E. Nakamura, Y. Hamasaki, K. Doi, M. Nangaku, E. Noiri, Sci. Rep., in press.

48. Synthesis and Characterization of a Well-Defined Carbon Nanohorn-Supported Molybdenum Dioxo Catalyst by SMART-EM Imaging. Surface Structure at the Atomic Level, Y. Kratish, T. Nakamuro, Y. Liu, J. Li, I. Tomotsuka, K. Harano, E. Nakamura, T. Marks, Bull. Chem. Soc. Jpn., in press.

47. Aryl Radical Addition to Curvatures of Carbon Nanohorns for Single-Molecule-Level Molecular Imaging, K. Kamei, T. Shimizu, K. Harano, E. Nakamura, Bull. Chem. Soc. Jpn., 93, 1603-1608 (2020).

46. Ultra-fast Electron Microscopic Imaging of Single Molecules with Direct Electron Detection Camera and Noise Reduction, J. Stuckner, T. Shimizu, K. Harano, E. Nakamura, M. Murayama, Microsc. Microanal., 26, 667–675 (2020).

45. Real-time Video Imaging of Mechanical Motions of a Single Molecular Shuttle with Sub-millisecond Sub-angstrom Precision, T. Shimizu, D. Lungerich, J. Stuckner, M. Murayama, K. Harano, E. Nakamura, Bull. Chem. Soc. Jpn., 93, 1079-1085 (2020). (BCSJ Award Article, Open Access, Selected as Cover Picture)

44. Spiro-conjugated Carbon/Heteroatom-bridged p-Phenylenevinylenes: Synthesis, Properties, and Microcrystal Electron Crystallographic Analysis of Racemic Solid Solutions, H. Hamada, T. Nakamuro, K. Yamashita, H. Yanagisawa, O. Nureki, M. Kikkawa, K. Harano, R. Shang, E. Nakamura, Bull. Chem. Soc. Jpn., 93, 776–782 (2020). (BCSJ Award Article, Open Access, Selected as Cover Picture)

43. Cyclodextrins as Surfactants for Solubilization and Purification of Carbon Nanohorn Aggregates, H. Hanayama, J. Yamada, K. Harano, E. Nakamura, Chem. Asian J., 15, 1549–1552 (2020).

42. Bifurcation of Self-Assembly Pathways to Sheet or Cage Controlled by Kinetic Template Effect, L. H. Foianesi-Takeshige, S. Takahashi, T. Tateishi, R. Sekine, A. Okazawa, W. Zhu, T. Kojima, K. Harano, E. Nakamura, H. Sato, S. Hiraoka, Commun. Chem., 2, 128 (2019).

41. Atomistic Structures and Dynamics of Prenucleation Clusters in MOF-2 and MOF-5 Syntheses, J. Xing, L. Schweighauser, S. Okada, K. Harano, E. Nakamura, Nat. Commun., 10, 3608 (2019).

40. Preparation of Hierarchically Assembled Silver Nanostructures based on the Morphology of Crystalline Peptide‐Silver(I) Complexes, R. Miyake, Y. Nitanai, Y. Nakagawa, J. Xing, K. Harano, E. Nakamura, J. Okabayashi, T. Minamikawa, K. Uruma, K. Kanaizuka, M. Kurihara, ChemPlusChem, 84, 295–301 (2019). (Highlighted in ChemistryViews)

39. Pyrazine-Incorporated Graphdiyne Nanofilm as a Metal-Free Electrocatalyst for Hydrogen Evolution Reaction, R. Sakamoto, R. Shiotsuki, K. Wada, N. Fukui, H. Maeda, J. Komeda, R. Sekine, K. Harano, H. Nishihara, J. Mater. Chem. A., 6, 22189-22194 (2018).

38. Neutron Scattering Reveals Water Confined in a Watertight Bilayer Vesicle, W. Abuillan, A. S. Becker, B. Demé, T. Homma, H. Isobe, K. Harano, E. Nakamura, M. Tanaka, J. Am. Chem. Soc., 140, 11261-11266 (2018).

37. Hierarchical Assembly of siRNA with Tetraamino Fullerene in Physiological Conditions for Efficient Internalization into Cells and Knockdown, K. Minami, K. Okamoto, K. Harano, E. Noiri, E. Nakamura, ACS Appl. Mater. Interfaces, 10, 19347-19534 (2018).

36. Flexibility of Components Alters the Self-assembly Pathway of Pd₂L₄ Coordination Cages, S. Kai, S. P. Maddala, T. Kojima, S. Akagi, K. Harano, E. Nakamura, S. Hiraoka, Dalton Trans., 47, 3258-3263 (2018). (Selected as Front cover)

35. Acid-Responsive Conductive Nanofiber of Tetrabenzoporphyrin Made by Solution Processing, Y. Zhen, K. Inoue, Z. Wang, T. Kusamoto, K. Nakabayashi, S. Ohkoshi, W. Hu, Y. Guo, K. Harano, E. Nakamura, J. Am. Chem. Soc., 140, 62-65 (2018). (Selected as Cover picture)

34. Direct Microscopic Analysis of Individual C₆₀ Dimerization Events: Kinetics and Mechanisms, S. Okada, S. Kowashi, L. Schweighauser, K. Yamanouchi, K. Harano, E. Nakamura, J. Am. Chem. Soc., 139, 18281-18287 (2017).

33. Bis(dipyrrinato)zinc(II) Complex Chiroptical Wires: Exfoliation into Single Strands and Intensification of Circularly Polarized Luminescence, R. Aoki, R. Toyoda, J. F. Kögel, R. Sakamoto, J. Kumar, Y. Kitagawa, K. Harano, T. Kawai, H. Nishihara, J. Am. Chem. Soc., 139, 16024-16027 (2017).

32. Experimental Study on Interconversion between Cubic MOF-5 and Square MOF-2 Arrays, L. Schweighauser, K. Harano, E. Nakamura, Inorg. Chem. Commun., 84, 1-4 (2017).

31. Conical Ionic Amphiphiles Endowed with Micellization Ability but Lacking Air- and Oil-Water Interfacial Activity, H. Nitta, K. Harano, M. Isomura, E. H. G. Backus, M. Bonn, E. Nakamura, J. Am. Chem. Soc., 139, 7677-7680 (2017).

30. Heterogeneous Catalase-like Activity of Gold(I)-Cobalt(III) Metallosupramolecular Ionic Crystals, M. Yamada, N. Yoshinari, N. Kuwamura, T. Saito, S. Okada, S. P. Maddala, K. Harano, E. Nakamura, K. Yamagami, K. Yamanaka, A. Sekiyama, T. Suenobu, Y. Yamada, T. Konno, Chem. Sci., 8, 2671-2676 (2017).

29. Supramolecular Differentiation for Constructing Anisotropic Fullerene Nanostructures by Time-Programmed Control of Interfacial Growth, P. Bairi, K. Minami, J. P. Hill, W. Nakanishi, L. K. Shrestha, C. Liu, K. Harano, E. Nakamura, K. Ariga, ACS Nano, 10, 8796-8802 (2016).

28. Nanoscale Control of Polymer Assembly on a Synthetic Catalyst-Bilayer System, R. M. Gorgoll, K. Harano, E. Nakamura, J. Am. Chem. Soc., 138, 9675-9681 (2016).

27. Chemical Pathways Connecting Lead(II) Iodide and Perovskite via Polymeric Plumbate(II) Fiber, Y. Guo, K. Shoyama, W. Sato, Y. Matsuo, K. Inoue, K. Harano, C. Liu, H. Tanaka, E. Nakamura, J. Am. Chem. Soc., 137, 15907-15914 (2015).

26. Cooperative Self-Assembly of Gold Nanoparticles on the Hydrophobic Surface of Vesicles in Water, R. M. Gorgoll, T. Tsubota, K. Harano, E. Nakamura, J. Am. Chem. Soc., 137, 7568-7571 (2015).

25. Electron Microscopic Observation of Selective Excitation of Conformational Change of a Single Organic Molecule, R. M. Gorgoll, E. Yücelen, A. Kumamoto, N. Shibata, K. Harano, E. Nakamura, J. Am. Chem. Soc., 137, 3474-3477 (2015).

24. Organic Solid Solution Composed of Two Structurally Similar Porphyrins for Organic Solar Cells, Y. Zhen, H. Tanaka, K. Harano, S. Okada, Y. Matsuo, E. Nakamura, J. Am. Chem. Soc., 137, 2247-2252 (2015).

23. DNA Binding of Pentaamino[60]fullerene Synthesized using Click Chemistry, H. Niita, K. Minami, K. Harano, E. Nakamura, Chem. Lett., 44, 378-380 (2015). (Selected as Editor's Choice, open-access article)

22. High-Density Display of Protein Ligands on Self-Assembled Capsules via Noncovalent Fluorous Interactions, K. Harano, J. Yamada, S. Mizuno, E. Nakamura, Chem. Asian J., 10, 172-176 (2015).

21. Fabrication of NIR-Excitable SERS-Active Composite Particles Comprised of Densely-Packed Au Nanoparticles on Polymer Microparticles, M. Kanahara, H. Satoh, T. Higuchi, A. Takahara, H. Jinnai, K. Harano, S. Okada, E. Nakamura, Y. Matsuo, H. Yabu, Part. Part. Syst. Charact., 32, 441-447 (2015). (Selected as Cover Picture)

20. Enhancement in the Efficiency of an Organic-Inorganic Hybrid Solar Cell with a Doped P3HT Hole-Transporting Layer on a Void-Free Perovskite Active Layer, Y. Guo, C. Liu, K. Inoue, K. Harano, H. Tanaka, E. Nakamura, J. Mater. Chem. A, 2, 13827-13830 (2014).

19. siRNA Delivery Targeting to the Lung via Agglutination-Induced Accumulation and Clearance of Cationic Tetraamino Fullerene, K. Minami, K. Okamoto, K. Doi, K. Harano, E. Noiri, E. Nakamura, Sci. Rep., 4, 4916 (2014).

18. Formation of a Polycrystalline Film of Donor Material on PEDOT:PSS Buffer Induced by Crystal Nucleation, K. Harano, S. Okada, S. Furukawa, H. Tanaka, E. Nakamura, J. Polym. Sci. Part B: Polym. Phys., 52, 833-841 (2014).

17. Photo-cross-linking of Exterior of Fullerene Bilayer that Prevents Vesicle Aggregation, K. Harano, A. Narita, E. Nakamura, Chem. Lett., 43, 877-879 (2014). (Selected as Editor's Choice and Cover Picture, open-access article)

16. Conformational Analysis of Single Perfluoroalkyl Chains by Single-Molecule Real-Time Transmission Electron Microscopic Imaging, K. Harano, S. Takenaga, S. Okada, Y. Niimi, N. Yoshikai, H. Isobe, K. Suenaga, H. Kataura, M. Koshino, E. Nakamura, J. Am. Chem. Soc., 136, 466-473 (2014).

15. Binding of Aromatic Molecules in the Fullerene-Rich Interior of a Fullerene Bilayer Vesicle in Water, K. Harano, R. M. Gorgoll, E. Nakamura, Chem. Commun., 49, 7629-7631 (2013).

14. Photocrosslinking of Fullerene Vesicles that Prevents Phase Transition and Decreases Water Permeation, K. Harano, A. Narita, E. Nakamura, Chem. Lett., 42, 1176-1178 (2013). (Selected as Editor's Choice, open-access article)

13. Polymer Janus Particles Containing Block-Copolymer Stabilized Magnetic Nanoparticles, H. Yabu, M. Kanahara, M. Shimomura, T. Arita, K. Harano, E. Nakamura, T. Higuchi, H. Jinnai, ACS Appl. Mater. Interfaces, 5, 3262-3266 (2013).

12. Protein-Coated Nanocapsules via Multilevel Surface Modification. Controlled Preparation and Microscopic Analysis at Nanometer Resolution, K. Harano, K. Minami, E. Noiri, K. Okamoto, E. Nakamura, Chem. Commun., 49, 3525-3527 (2013).

11. Heterogeneous Nucleation of Organic Crystals Mediated by Single-Molecule Templates, K. Harano, T. Homma, Y. Niimi, M. Koshino, K. Suenaga, L. Leibler, E. Nakamura, Nat. Mater., 11, 877-881 (2012). (Highlighted in News and Views, Nat. Mater., 11, 838-840 (2012).)

10. Preparation and Properties of Vesicles Made of Nonpolar/Polar/Nonpolar Fullerene Amphiphiles, T. Homma, K. Harano, H. Isobe, E. Nakamura, J. Am. Chem. Soc., 133, 6364-6370 (2011).

9. Nanometer-Sized Fluorous Fullerene Vesicles in Water and on Solid Surfaces, T. Homma, K. Harano, H. Isobe, E. Nakamura, Angew. Chem. Int. Ed., 49, 1665-1668 (2010).

8. Induced-Fit Formation of a Tetrameric Organic Capsule Consisting of Hexagram-Shaped Amphiphile Molecules, S. Hiraoka, K. Harano, T. Nakamura, M. Shiro, M. Shionoya, Angew. Chem., Int. Ed., 48, 7006-7009 (2009).

7. A Self-Assembled Organic Capsule Formed from the Union of Six Hexagram-Shaped Amphiphile Molecules, S. Hiraoka, K. Harano, M. Shiro, M. Shionoya, J. Am. Chem. Soc., 130, 14368-14369 (2008).

6. Mono- and Penta-Addition of Enol Silyl Ethers to [60]Fullerene, E. Nakamura, S. Mouri, Y. Nakamura, K. Harano, and H. Isobe, Org. Lett., 10, 4923-4926 (2008).

5. Imaging of Conformational Change of Biotinylated Triamide Molecules Covalently Bonded to Carbon Nanotube Surface, E. Nakamura, M. Koshino, T. Tanaka, Y. Niimi, K. Harano, Y. Nakamura, and H. Isobe, J. Am. Chem. Soc., 130, 7808-7809 (2008).

4. 3 nm-Scale Molecular Switching between Fluorescent Coordination Capsule and Nonfluorescent Cage, K. Harano, S. Hiraoka, M. Shionoya, J. Am. Chem. Soc., 129, 5300-5301. (2007)

3. Isostructural Coordination Capsules for a Series of Ten Different d⁵-d¹⁰ Transition-Metal Ions, S. Hiraoka, K. Harano, M. Shiro, Y. Ozawa, N. Yasuda, K. Toriumi, M. Shionoya, Angew. Chem., Int. Ed., 45, 6488-6491 (2006). (selected as VIP and Cover Picture)

2. Quantitative Dynamic Interconversion between Ag^I-Mediated Capsule and Cage Complexes Accompanying Guest Encapsulation/Release, S. Hiraoka, K. Harano, M. Shiro, M. Shionoya, Angew. Chem., Int. Ed., 44, 2727-2731 (2005).

1. Quantitative Formation of Sandwich-Shaped Trinuclear Silver(I) Complexes and Dynamic Feature of Their P↔M Flip Motion in Solution, S. Hiraoka, K. Harano, T. Tanaka, M. Shiro, M. Shionoya, Angew. Chem., Int. Ed., 42, 5182-5185 (2003).

Review/Account:

4. Self-Assembly Mechanism in Nucleation Processes of Molecular Crystalline Materials, K. Harano, Bull. Chem. Soc. Jpn., in press.

3. Interfacial Chemistry of Conical Fullerene Amphiphiles in Water, K. Harano, E. Nakamura, Acc. Chem. Res., 52, 2090−2100 (2019).

2. Chemical Kinetics Study through Observation of Individual Reaction Events with Atomic-Resolution Electron Microscopy, E. Nakamura, K. Harano, Proc. Jpn. Acad., Ser. B, 94, 428−440 (2018). (Selected as Cover)

1. 結晶はどのようにしてできるか，原野幸治，化学と教育, 63, 384-387 (2015).

著書 :

2. Koji Harano, Eiichi Nakamura, Conformational Analysis of Organic Molecules with Single-Molecule Atomic-Resolution Real-Time Transmission Electron Microscopy (SMART-TEM) Imaging. In Molecular Technology, Volume 4: Synthesis Innovation, Eds: H. Yamamoto, T. Kato, pp 339-368, Wiley-VCH, (2019).

1. π電子研究の歴史と将来展望（分担執筆），原野幸治，中村栄一，未来材料を創出するπ電子系の化学（CSJカレントレビュー12），化学同人，20-24 (2013).

記事・解説 :

8. 世界最高速の動画撮影でひもとく分子の世界-カメラは見た！分子が動く決定的瞬間-，清水俊樹, 原野幸治，中村栄一，化学, 75(11), 12-16 (2020).

7. 単分子原子分解能実時間電子顕微鏡法による化学反応研究，原野幸治, 中村栄一，化学と工業, 73, 16-18 (2020).

6. アスファルテン分子の可視化，原野幸治，日本エネルギー学会機関誌えねるみくす, 98, 676-682 (2019).

5. 目に見えない微結晶の構造を解析する！ -マイクロ電子回折で三次元分子構造を決定，原野幸治，劉東欣，中室貴幸，中村栄一，化学, 74(5), 49-53 (2019).

4. 化学反応を顕微鏡で追跡する時代が到来，岡田　賢，山内　薫，原野幸治，中村栄一，現代化学, 566, 27-31 (2018).

3. 原子分解能顕微鏡で化学反応機構を調べる！-一体いくつの分子を調べればよいのだろうか-，岡田　賢，山内　薫，原野幸治，中村栄一，化学, 73(4), 12-16 (2018).

2. お茶のなかの分子世界，原野幸治，現代化学, 556, 384-387 (2017).

1. 外部刺激に応答して伸縮する配位高分子錯体，原野幸治，化学と工業, 58, 593 (2005).