論文・学会発表 | 高野　慎二郎

原著論文

  1. "Cyclic ion mobility of doped [MAu24L18]2- superatoms and their fragments (M = Ni, Pd and Pt; L = alkynyl)"
    Frank Hennrich, Shun Ito, Patrick Weis, Marco Neumaier, Shinjiro Takano, Tatsuya Tsukuda, and Manfred M. Kappes*
    Phys. Chem. Chem. Phys., 26, 8408-8418 (2024).
  2. "Diphosphine-Protected IrAu12 Superatom with Open Site(s): Synthesis and Programmed Stepwise Assembly"
    Yuto Fukumoto, Tsubasa Omoda, Haru Hirai, Shinjiro Takano, Koji Harano, and Tatsuya Tsukuda*
    Angew. Chem., Int. Ed., e202402025 (2024).
  3. "Introducing Iodide Ligands on IrAu12 Cluster Enhances Phosphorescence Efficiency and Photoredox Activity"
    Haru Hirai, Shinjiro Takano, Shinya Masuda, and Tatsuya Tsukuda*
    ChemElectroChem, 11, e202300669 (2024).
  4. "Enantiopure Chiral Au13 Nanoclusters Stabilized by Ditopic N-Heterocyclic Carbenes: Synthesis, Characterization, and Electrocatalytic Reduction of CO2"
    Emily L. Albright, Sami Malola, Samuel I. Jacob, Hong Yi, Shinjiro Takano, Koichi Mimura, Tatsuya Tsukuda*, Hannu Häkkinen*, Masakazu Nambo*, and Cathleen M. Crudden*
    Chem. Mater., 36, 1279-1289 (2024).
  5. "Clarifying the Electronic Structure of Anion-Templated Silver Nanoclusters by Optical Absorption Spectroscopy and Theoretical Calculation"
    Yusuke Horita, Sakiat Hossain*, Mai Ishimi, Pei Zhao, Miyu Sera, Tokuhisa Kawawaki, Shinjiro Takano, Yoshiki Niihori, Toshikazu Nakamura, Tatsuya Tsukuda, Masahiro Ehara*, and Yuichi Negishi*
    J. Am. Chem. Soc., 145, 23533-23540 (2023).
  6. "Au13 Superatom Bearing Two Terpyridines at Coaxial Positions: Photoluminescence Quenching via Complexation with 3d Metal Ions"
    Naoki Kito, Shinjiro Takano, Shinya Masuda, Koji, Harano, and Tatsuya Tsukuda*
    Bull. Chem. Soc. Jpn., 96, 1045-1051 (2023).
  7. "Collision-Induced Fission of Oblate Gold Superatom in [Au9(PPh3)8]3+: Deformation-Mediated Mechanism"
    Satoru Muramatsu*, Yuki Nakahigashi, Tsubasa Omoda, Shinjiro Takano, Tatsuya Tsukuda*, and Yoshiya Inokuchi*
    J. Phys. Chem. Lett., 14, 5641-5647 (2023).
  8. "Synthesis and Characterization of a Monodentate N-Heterocyclic Carbene-Protected Au11-Nanocluster via Reduction with KC8"
    Angus I. Sullivan, Joseph F. DeJesus, Sami Malola, Shinjiro Takano, Tatsuya Tsukuda*, Hannu Häkkinen*, and Cathleen M. Crudden*
    Chem. Mater., 35, 2790-2796 (2023).
  9. "Bioconjugation of Au25 Nanocluster to Monoclonal Antibody at Tryptophan"
    Katarzyna Joanna Malawska, Shinjiro Takano, Kounosuke Oisaki*, Haruaki Yanagisawa, Masahide Kikkawa, Tatsuya Tsukuda, and Motomu Kanai*
    Bioconjugate Chem., 34, 781-788 (2023).
  10. "Effect of Group-10 Element M (Ni, Pd, Pt) on Electronic Structure of Icosahedral M@Au12 Cores of MAu24L18 (L = Alkynyl, Thiolate)"
    Shinjiro Takano*, Emi Ito, Toshikazu Nakamura, and Tatsuya Tsukuda*
    J. Phys. Chem. C, 127, 4360-4366 (2023).
  11. "Partially Thiolated Au25 Cluster Anchored on Carbon Support via Noncovalent Ligand-Support Interactions: Active and Robust Catalyst for Aerobic Oxidation of Alcohols"
    Kosuke Sakamoto, Shinya Masuda, Shinjiro Takano, and Tatsuya Tsukuda*
    ACS Catal., 13, 3263-3271 (2023).
  12. "IrAu12 superatom modified by chiral diphosphines: Doping-induced enhancement of chiroptical activity"
    Haru Hirai, Takuya Nakashima*, Shinjiro Takano, Yukatsu Shichibu, Katsuaki Konishi*, Tsuyoshi Kawai, and Tatsuya Tsukuda*
    J. Mater. Chem. C, 11, 3095-3100 (2023).
  13. "Spontaneous Intercluster Electron Transfer X2– + X0 → 2 X– (X = PtAu24(SCnH2n+1)18) in Solution: Promotion by Long Alkyl Chains"
    Megumi Suyama, Shinjiro Takano, and Tatsuya Tsukuda*
    J. Am. Chem. Soc., 145, 3361-3368 (2023).
  14. "Supervalence Bonding in Bi-icosahedral Cores of [M1Au37(SC2H4Ph)24]– (M = Pd and Pt): Fusion-Mediated Synthesis and Anion Photoelectron Spectroscopy"
    Emi Ito, Shun Ito, Shinjiro Takano, Toshikazu Nakamura, and Tatsuya Tsukuda*
    JACS Au, 2, 2627-2634 (2022).
  15. "Synergistically Activated Pd Atom in Polymer-Stabilized Au23Pd1 Cluster"
    Shingo Hasegawa, Shinya Masuda, Shinjiro Takano, Koji Harano, Jun Kikkawa, and Tatsuya Tsukuda*
    ACS Nano, 16, 16932-16940 (2022).
  16. "Doping-Mediated Energy-Level Engineering of M@Au12 Superatoms (M = Pd, Pt, Rh, Ir) for Efficient Photoluminescence and Photocatalysis"
    Haru Hirai, Shinjiro Takano, Takuya Nakashima, Takeshi Iwasa, Tetsuya Taketsugu, and Tatsuya Tsukuda*
    Angew. Chem., Int. Ed., 61, e202207290 (2022).
  17. "Polymer-Stabilized Au38 Cluster: Atomically Precise Synthesis by Digestive Ripening and Characterization of the Atomic Structure and Oxidation Catalysis"
    Shingo Hasegawa, Shinya Masuda, Shinjiro Takano, Koji Harano, and Tatsuya Tsukuda*
    ACS Catal., 12, 6550-6558 (2022).
  18. "N-Heterocyclic Carbene-Stabilized Hydrido Au24 Nanoclusters: Synthesis, Structure, and Electrocatalytic Reduction of CO2"
    Viveka K. Kulkarni, Behnam Nourmohammadi Khiarak, Shinjiro Takano, Sami Malola, Emily L. Albright, Tetyana I. Levchenko, Mark D. Aloisio, Cao-Thang Dinh*, Tatsuya Tsukuda*, Hannu Häkkinen*, and Cathleen M. Crudden*
    J. Am. Chem. Soc., 144, 9000-9006 (2022).
  19. "NHC-Stabilized Au10 Nanoclusters and Their Conversion to Au25 Nanoclusters"
    Paul A. Lummis, Kimberly M. Osten, Tetyana I. Levchenko, Maryam Sabooni Asre Hazer, Sami Malola, Bryan Owens-Baird, Alex J. Veinot, Emily L. Albright, Gabriele Schatte, Shinjiro Takano, Kirill Kovnir*, Kevin G. Stamplecoskie*, Tatsuya Tsukuda*, Hannu Häkkinen*, Masakazu Nambo*, and Cathleen M. Crudden*
    JACS Au, 2, 875-885 (2022).
  20. "Synthesis and Characterization of Enantiopure Chiral Bis NHC-Stabilized Edge-Shared Au10 Nanocluster with Unique Prolate Shape"
    Renee W. Y. Man, Hong Yi, Sami Malola, Shinjiro Takano, Tatsuya Tsukuda*, Hannu Häkkinen*, Masakazu Nambo*, and Cathleen M. Crudden*
    J. Am. Chem. Soc., 144, 2056-2061 (2022).
  21. "Synthesis of active, robust and cationic Au25 cluster catalysts on double metal hydroxide by long-term oxidative aging of Au25(SR)18"
    Shinya Masuda, Shinjiro Takano, Seiji Yamazoe and Tatsuya Tsukuda*
    Nanoscale, 14, 3031-3039 (2022).
  22. "A Face-to-Face Dimer of Au3 Superatoms Supported by Interlocked Tridentate Scaffolds Formed in Au18S2(SR)12"
    Taro Shigeta, Shinjiro Takano, and Tatsuya Tsukuda*
    Angew. Chem., Int. Ed., 61, e202113275 (2022).
  23. "Decorating an Anisotropic Au13 Core with Dendron Thiolates: Enhancement of Optical Absorption and Photoluminescence"
    Tsubasa Omoda, Shinjiro Takano, Shinya Masuda and Tatsuya Tsukuda*
    Chem. Commun., 57, 12159 (2021).
  24. "Critical Role of CF3 Groups in the Electronic Stabilization of [PdAu24(C≡CC6H3(CF3)2)18]2- as Revealed by Gas-Phase Anion Photoelectron Spectroscopy"
    Shun Ito, Kiichirou Koyasu, Shinjiro Takano, and Tatsuya Tsukuda*
    J. Phys. Chem. Lett., 12, 10417 (2021).
  25. "Ligand Effects on the Hydrogen Evolution Reaction Catalyzed by Au13 and Pt@Au12: Alkynyl vs Thiolate"
    Xiang Li, Shinjiro Takano, and Tatsuya Tsukuda*
    J. Phys. Chem. C, 125, 23226-23230 (2021).
  26. "Chemical Transformations of [MAu8(PPh3)8]2+ (M = Pt, Pd) and [Au9(PPh3)8]3+ in Methanol Induced by Irradiation of Atmospheric Pressure Plasma"
    Sojiro Emori, Shinjiro Takano, Kiichirou Koyasu, and Tatsuya Tsukuda*
    J. Chem. Phys., 155, 124312 (2021).
  27. "Synergistic Effect in Ir- or Pt-Doped Ru Nanoparticles: Catalytic Hydrogenation of Carbonyl Compounds under Ambient Temperature and H2 Pressure"
    Shotaro Matsuda, Shinya Masuda, Shinjiro Takano, Nobuyuki Ichikuni, and Tatsuya Tsukuda*
    ACS Catal., 11, 10502-10507 (2021).
  28. "Effects of π-Electron Systems on Optical Activity of Au11 Clusters Protected by Chiral Diphosphines"
    Naoaki Shinjo, Shinjiro Takano, and Tatsuya Tsukuda*
    Bull. Korean Chem. Soc., 42, 1265-1268 (2021).
  29. "Photoluminescence of Doped Superatoms M@Au12 (M = Ru, Rh, Ir) Homoleptically Capped by (Ph2)PCH2P(Ph2): Efficient Room-Temperature Phosphorescence from Ru@Au12"
    Shinjiro Takano, Haru Hirai, Takuya Nakashima, Takeshi Iwasa, Tetsuya Taketsugu, and Tatsuya Tsukuda*
    J. Am. Chem. Soc., 143, 10560-10564 (2021).
  30. "Atomically-Ordered Trimetallic Superatoms M@Au6Ag6 (M = Pd, Pt): Synthesis and Photoluminescence Properties"
    Shinjiro Takano, and Tatsuya Tsukuda*
    Chem. Lett., 50, 1419-1422 (2021).
  31. "Ligand Effects on the Structures of [Au23L6(C≡CPh)9]2+ (L = N-Heterocyclic Carbene vs Phosphine) with Au17 Superatomic Cores"
    Koto Hirano, Shinjiro Takano, and Tatsuya Tsukuda*
    J. Phys. Chem. C, 125, 9930 (2021).
  32. "New Magic Au24 Cluster Stabilized by PVP: Selective Formation, Atomic Structure, and Oxidation Catalysis"
    Shingo Hasegawa, Shinjiro Takano, Koji Harano, and Tatsuya Tsukuda*
    JACS Au, 1, 660 (2021).
  33. "Few-nm-Sized, Phase-Pure Au5Sn Intermetallic Nanoparticles: Synthesis and Characterization"
    Satoshi Osugi, Shinjiro Takano, Shinya Masuda, Koji Harano, and Tatsuya Tsukuda*
    Dalton Trans., 50, 5177 (2021).
  34. "Synergistic Effects of Pt and Cd Codoping to Icosahedral Au13 Superatoms"
    Megumi Suyama, Shinjiro Takano, and Tatsuya Tsukuda*
    J. Phys. Chem. C, 124, 23923 (2020).
  35. "Controlled Dimerization and Bonding Scheme of Icosahedral M@Au12 (M = Pd, Pt) Superatoms"
    Emi Ito, Shinjiro Takano*, Toshikazu Nakamura and Tatsuya Tsukuda*
    Angew. Chem., Int. Ed., 60, 645 (2021).
  36. "Collision-Induced Reductive Elimination of 1,3-Diynes from [MAu24(C≡CR)18]2– (M = Pd, Pt) Yielding Clusters of Superatoms"
    Shun Ito, Kiichirou Koyasu, Shinjiro Takano, and Tatsuya Tsukuda*
    J. Phys. Chem. C, 124, 19119 (2020).
  37. "Electron-Rich Gold Clusters Stabilized by Polyvinylpyridines as Robust and Active Oxidation Catalysts"
    Atsushi Matsuo, Shingo Hasegawa, Shinjiro Takano, and Tatsuya Tsukuda*
    Langmuir, 36, 7844-7849 (2020).
  38. Understanding Doping Effects on Electronic Structures of Gold Superatoms: A Case Study of Diphosphine-Protected M@Au12 (M = Au, Pt, Ir)"
    Haru Hirai, Shinjiro Takano,Toshikazu Nakamura and Tatsuya Tsukuda*
    Inorg. Chem., 59, 17889 (2020).
  39. "Electron Microscopic Observation of an Icosahedral Au13 Core in Au25(SeR)18 and Reversible Isomerization between Icosahedral and Face-Centered Cubic Cores in Au144(SC2H4Ph)60"
    Ryo Takahata, Seiji Yamazoe, Yosuke Maehara, Kenji Yamazaki, Shinjiro Takano, Wataru Kurashige, Yuichi Negishi, Kazutoshi Gohara and Tatsuya Tsukuda*
    J. Phys. Chem. C, 124, 6907 (2020).
  40. "Asymmetric Aerobic Oxidation of Secondary Alcohols Catalyzed by Poly(N-vinyl-2-pyrrolidone)-stabilized Gold Clusters Modified with Cyclodextrin Derivatives"
    Koto Hirano, Shinjiro Takano, and Tatsuya Tsukuda*
    Chem. Commun., 55, 15033-15036 (2019).
  41. "Alkynyl-Protected Au22(C≡CR)18 Clusters Featuring New Interfacial Motifs and R-Dependent Photoluminescence"
    Shun Ito, Shinjiro Takano, and Tatsuya Tsukuda*
    J. Phys. Chem. Lett., 10, 6892-6896 (2019).
  42. "Efficient and Selective Conversion of Phosphine-Protected (MAu8)2+ (M = Pd, Pt) Superatoms to Thiolate-Protected (MAu12)6+ or Alkynyl-Protected (MAu12)4+ Superatoms via Hydride Doping"
    Shinjiro Takano*, Shun Ito, and Tatsuya Tsukuda*
    J. Am. Chem. Soc., 141, 15994-16002 (2019).
  43. "Robust, Highly Luminescent Au13 Superatoms Protected by N-Heterocyclic Carbenes"
    Mina R. Narouz, Shinjiro Takano, Paul A. Lummis, Tetyana I. Levchenko, Ali Nazemi, Sami Kaappa, Sami Malola, Goonay Yousefalizadeh, Larry A. Calhoun, Kevin G. Stamplecoskie*, Hannu Häkkinen*, Tatsuya Tsukuda*, and Cathleen M. Crudden*
    J. Am. Chem. Soc., 141, 14997-15002 (2019).
  44. "Stoichiometric Formation of Open-Shell [PtAu24(SC2H4Ph)18]– via Spontaneous Electron Proportionation between [PtAu24(SC2H4Ph)18]2– and [PtAu24(SC2H4Ph)18]0"
    Megumi Suyama, Shinjiro Takano, Toshikazu Nakamura and Tatsuya Tsukuda*
    J. Am. Chem. Soc., 141, 14048-14051 (2019).
  45. "Reduction-Resistant [Au25(cyclohexanethiolate)18]0 with an Icosahedral Au13 Core"
    Tsubasa Omoda, Shinjiro Takano and Tatsuya Tsukuda*
    Chem. Lett., 48, 885-887 (2019).
  46. "N-heterocyclic carbene-functionalized magic-number gold nanoclusters"
    Mina R. Narouz, Kimberly M. Osten, Phillip J. Unsworth, Renee W. Y. Man, Kirsi Salorinne, Shinjiro Takano, Ryohei Tomihara, Sami Kaappa, Sami Malola, Cao-Thang Dinh, J. Daniel Padmos, Kennedy Ayoo, Patrick J. Garrett, Masakazu Nambo, J. Hugh Horton, Edward H. Sargent, Hannu Häkkinen*, Tatsuya Tsukuda* and Cathleen M. Crudden*
    Nature Chemistry, 11, 419-425 (2019).
  47. "Synthesis of trimetallic (HPd@M2Au8)3+ superatoms (M = Ag, Cu) via hydride-mediated regioselective doping to (Pd@Au8)2+"
    Haru Hirai, Shinjiro Takano, and Tatsuya Tsukuda*
    ACS Omega, 4, 7070-7075 (2019).
  48. "Interconversions of Structural Isomers of [PdAu8(PPh3)8]2+ and [Au9(PPh3)8]3+ Revealed by Ion Mobility Mass Spectrometry"
    Keisuke Hirata, Papri Chakraborty, Abhijit Nag, Shinjiro Takano, Kiichirou Koyasu, Thalappil Pradeep* and Tatsuya Tsukuda*
    J. Phys. Chem. C, 122, 23123-23128 (2018).
  49. "Hydride-Mediated Controlled Growth of a Bimetallic (Pd@Au8)2+ Superatom to a Hydride-Doped (HPd@Au10)3+ Superatom"
    Shinjiro Takano, Haru Hirai, Satoru Muramatsu, and Tatsuya Tsukuda*
    J. Am. Chem. Soc., 140, 12314-12317 (2018).
  50. "Hydride-Doped Gold Superatom (Au9H)2+: Synthesis, Structure and Transformation"
    Shinjiro Takano, Haru Hirai, Satoru Muramatsu, and Tatsuya Tsukuda*
    J. Am. Chem. Soc., 140, 8380-8383 (2018).
  51. "An Au25(SR)18 Cluster with a Face-Centered Cubic Core"
    Tsubasa Omoda, Shinjiro Takano, Seiji Yamazoe, Kiichirou Koyasu, Yuichi Negishi, and Tatsuya Tsukuda*
    J. Phys. Chem. C, 122, 24, 13199-13204 (2018).
  52. "Collision-Induced Dissociation of Undecagold Clusters Protected by Mixed Ligands [Au11(PPh3)8X2]+ (X = Cl, C ≡ CPh)"
    Ryohei Tomihara, Keisuke Hirata, Hiroki Yamamoto, Shinjiro Takano, Kiichirou Koyasu, and Tatsuya Tsukuda*
    ACS Omega, 3, 6, 6237-6242 (2018).
  53. "Prominent hydrogenation catalysis of a PVP-stabilized Au34 superatom provided by doping a single Rh atom"
    Shingo Hasegawa, Shinjiro Takano, Seiji Yamazoe, and Tatsuya Tsukuda*
    Chem. Commun., 54, 5915-5918 (2018).
  54. "Anion Photoelectron Spectroscopy of Free [Au25(SC12H25)18]−"
    Keisuke Hirata, Kenshiro Yamashita, Satoru Muramatsu, Shinjiro Takano, Keijiro Ohshimo, Toshiyuki Azuma, Ryuzo Nakanishi, Takashi Nagata, Seiji Yamazoe, and Tatsuya Tsukuda*
    Nanoscale, 9, 13409-13412 (2017).
  55. "Metal Substitution Effect on a Three-Dimensional Cyanide-Bridged Fe Spin-Crossover Network"
    Kenta Imoto, Shinjiro Takano, and Shin-ichi Ohkoshi*
    Inorganics 5, 63 (2017).
  56. "Suppressing Isomerization of Phosphine–Protected Au9 Cluster by Bond Stiffening Induced by Single Pd Atom Substitution"
    Seiji Yamazoe, Shota Matsuo, Satoru Muramatsu, Shinjiro Takano, Kiyofumi Nitta, and Tatsuya Tsukuda*
    Inorg. Chem. 56, 8319-8325 (2017).
  57. "A Gold Superatom with 10 Electrons in Au13(PPh3)8(p-SC6H4CO2H)3"
    Shinjiro Takano, Seiji Yamazoe, and Tatsuya Tsukuda*
    APL. Mater. 5, 053402 (2017).
  58. "Amplification of Optical Activity of Gold Clusters by the Proximity of BINAP"
    Shinjiro Takano and Tatsuya Tsukuda*
    J. Phys. Chem. Lett. 7, 4509-4513 (2016).
  59. "Selective and High-Yield Synthesis of Oblate Superatom [PdAu8(PPh3)8]2+"
    Shota Matsuo, Shinjiro Takano, Seiji Yamazoe, Kiichirou Koyasu, and Tatsuya Tsukuda*
    ChemElectroChem 3, 1206 (2016).
  60. "Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates"
    Seiji Yamazoe, Shinjiro Takano, Wataru Kurashige, Toshihiko Yokoyama, Kiyofumi Nitta, Yuichi Negishi, and Tatsuya Tsukuda*
    Nature Communications 7, 10414 (2016).
  61. "Synthesis and Catalytic Application of Ag44 Clusters Supported on Mesoporous Carbon"
    Masaru Urushizaki, Hirokazu Kitazawa, Shinjiro Takano, Ryo Takahata, Seiji Yamazoe, and Tatsuya Tsukuda*
    J. Phys. Chem. C 119, 27483-27488 (2015).
  62. "Slow-reduction synthesis of a thiolate-protected one-dimensional gold cluster showing an intense near-infrared absorption"
    Shinjiro Takano, Seiji Yamazoe, Kiichirou Koyasu, and Tatsuya Tsukuda*
    J. Am. Chem. Soc. 137, 7027-7030 (2015).
  63. "A Critical Size for Emergence of Nonbulk Electronic and Geometric Structures in Dodecanethiolate-Protected Au Cluster"
    Yuichi Negishi*, Tafu Nakazaki, Sami Malola, Shinjiro Takano, Yoshiki Niihori, Wataru Kurashige, Seiji Yamazoe, Tatsuya Tsukuda*, and Hannu Häkkinen*
    J. Am. Chem. Soc. 137, 1206-1212 (2015).
  64. "Binding motif of terminal alkynes on gold clusters"
    Prasenjit Maity, Shinjiro Takano , Seiji Yamazoe, Tomonari Wakabayashi and Tatsuya Tsukuda
    J. Am. Chem. Soc. 135, 9450-9457 (2013).
  65. "90-degree optical switching of output second harmonic light in chiral photomagnet"
    Shin-ichi Ohkoshi, Shinjiro Takano , Kenta Imoto, Marie Yoshikiyo, Asuka Namai and Hiroko Tokoro
    Nature Photonics 8, 65 (2014).
  66. "Light-induced spin-crossover magnet"
    Shin-ichi Ohkoshi, Kenta Imoto, Yoshihide Tsunobuchi, Shinjiro Takano and Hiroko Tokoro
    Nature Chemistry 3, 564 (2011).

学会発表

  1. "ジホスフィン保護18電子系超原子M@Au12 (M = Re, W): 合成と構造評価", 高野慎二郎, 佃達哉, 第17回分子科学討論会, 大阪大学豊中キャンパス, 大阪, 2023年9月
  2. "18電子系超原子Re@Au12の合成と評価", 高野慎二郎, 佃達哉, ナノ学会第20回大会, 近畿大学, オンライン, 2022年5月
  3. "Development of Efficient and Selective Transformation Reactions of Hydride-Doped Gold Superatoms", Shinjiro Takano, Tatsuya Tsukuda, Pacifichem2021, Online, Dec. 2021. (Poster)
  4. "効率的な室温リン光を示すジホスフィン保護Ru@Au12超原子の合成と評価", 高野慎二郎, 平井遥, 中嶋琢也, 岩佐豪, 武次徹也, 佃達哉, 第15回分子科学討論会, 北海道大学, オンライン, 2021年9月
  5. "Development of precise transformation reactions of gold superatoms initiated by hydride doping",Shinjiro Takano, Shun Ito, Tatsuya Tsukuda, 日本化学会第100回春季年会, 東京理科大学野田キャンパス, 千葉, 2020年3月
  6. "ヒドリドドープ金超原子を利用した精密表面変換反応の開発", 高野慎二郎, 伊藤駿, 佃達哉, 第13回分子科学討論会, 名古屋大学東山キャンパス, 愛知, 2019年9月
  7. "ヒドリドドーピングを鍵とする金超原子の精密変換反応の開拓:表面化学修飾", 高野慎二郎, 伊藤駿, 佃達哉, ナノ学会第17回大会, かごしま県民交流センター, 鹿児島, 2019年5月
  8. "ヒドリドドープ金超原子の合成と評価", 高野慎二郎, 平井遥, 村松悟, 佃達哉, 第12回分子科学討論会, 福岡国際会議場, 福岡, 2018年9月
  9. "ヒドリドドープされた金超原子の生成と評価", 高野慎二郎, 平井遥, 村松悟, 佃達哉, ナノ学会第16回大会, 東京大学, 東京, 2018年5月
  10. "吸着水素を利用した金クラスターの成長制御", 高野慎二郎, 平井遥, 佃達哉, 第11回分子科学討論会, 東北大学, 宮城, 2017年9月
  11. "王冠型6 電子系金超原子の核成長反応", 高野慎二郎, 佃達哉, ナノ学会第15回大会, 北海道立道民活動センターかでる2・7, 北海道, 2017年5月
  12. "キラルホスフィン保護金クラスターの合成とその光学特性", 高野慎二郎, 佃達哉, 第10回分子化学討論会, 神戸ファッションマート, 兵庫, 2016年9月
  13. "A thiolate-protected gold cluster with strong near-IR absorption band: Synthesis and chracterization", Shinjiro Takano, Seiji Yamazoe, Kiichirou Koyasu and Tatsuya Tsukuda, GOLD 2015, Cardiff, UK, July 2015. (Poster)
  14. "Synthesis of a thiolate-protected one-dimensional gold cluster showing an intense NIR absorption band", Shinjiro Takano, Seiji Yamazoe, Kiichirou Koyasu and Tatsuya Tsukuda, ISMPC 15, Yamanashi, Japan, July 2015. (Oral)
  15. "チオラート保護一次元構造金クラスターの合成と光学特性", 高野慎二郎, 山添誠司, 小安喜一郎, 佃達哉, ナノ学会第13回大会, 東北大学, 宮城, 2015年5月.
  16. "面心立方構造の量子サイズ金クラスター：精密合成と近赤外線吸収バンドの観測", 高野慎二郎, 山添誠司, 小安喜一郎, 佃達哉, 第8回分子科学討論会, 広島大学, 広島, 2014年9月.
  17. "Novel Thiolate-protected Gold Clusters with Sub-2 nm Sized and Fcc cores: Synthesis and optical Property", Shinjiro Takano, Seiji Yamazoe, Kiichirou Koyasu and Tatsuya Tsukuda, ISSPIC XVII, Fukuoka, Japan, Sept. 2014. (poster)
  18. "fcc 構造を持つ量子サイズ金クラスターの合成と評価", 高野慎二郎, 山添誠司, 小安喜一郎, 佃達哉, 日本化学会第94春季年会, 名古屋大学, 愛知, 2014年3月.

総説・著書・解説

  1. "N-Heterocyclic Carbene-Stabilized Atomically Precise Metal Nanoclusters"
    Emily L. Albright, Tetyana I. Levchenko, Viveka K. Kulkarni, Angus I. Sullivan, Joseph F. DeJesus, Sami Malola, Shinjiro Takano, Masakazu Nambo*, Kevin Stamplecoskie*, Hannu Häkkinen*, Tatsuya Tsukuda*, and Cathleen M. Crudden*
    J. Am. Chem. Soc., 146, 5759-5780 (2024).
  2. "Bonding and Electronic Interactions of Hydrogen with Gold Superatoms"
    Subarna Maity, Shinjiro Takano, Shinya Masuda, and Tatsuya Tsukuda*
    J. Phys. Chem. C, 128, 19-30 (2024).
  3. 強発光性合金クラスターの創出に向けて
    高野慎二郎
    Bull. Jpn. Soc. Coord. Chem., 80, 49-53 (2022).
  4. 配位子保護金クラスターの標的合成法の開拓と物性制御指針の探究
    高野慎二郎
    Molecular Science, 16, A0121 (2022).
  5. 化学修飾された金属超原子の化学
    高野慎二郎・佃達哉
    フロンティアナノ金属錯体化学 (山下正廣, 小西克明編, 錯体化学会フロンティア選書, 三共出版, 2022) 108-132.
  6. Chapter6: "Atomically Precise Synthesis of Chemically Modified Superatoms
    Shinjiro Takano and Tatsuya Tsukuda
    in Superatoms: Principles, Synthesis, and Applications, edited by Puru Jena and Qiang Sun
    John Wiley & Sons, Hoboken (2022).
  7. "Chemically Modified Gold/Silver Superatoms as Artificial Elements at Nanoscale: Design Principles and Synthesis Challenges"
    Shinjiro Takano, and Tatsuya Tsukuda*
    J. Am. Chem. Soc., 143, 1683-1698 (2021).
  8. "Ligand-Protected Gold/Silver Superatoms: Current Status and Emerging Trends"
    Haru Hirai, Shun Ito, Shinjiro Takano, Kiichirou Koyasu and Tatsuya Tsukuda*
    Chem. Sci., 11, 12233 (2020).
  9. "Toward Controlling the Electronic Structures of Chemically Modified Superatoms of Gold and Silver"
    Tsubasa Omoda, Shinjiro Takano, and Tatsuya Tsukuda*
    Small, 17, 2001439 (2021).
  10. ヒドリドドーピングを鍵とする金超原子の精密変換反応の開拓：表面化学修飾
    11. 高野慎二郎・伊藤駿・佃達哉
    ナノ学会会報, 18, 31-36 (2020).　
  11. クラスター間の自発的電子移動による開殻系クラスター[PtAu24(SC2H4Ph)18]–の化学量論的生成
    12. 陶山めぐみ・ 高野慎二郎・ 中村敏和・佃達哉
    ナノ学会会報, 18, 21-26 (2019).　
  12. "Hydride Doping of Chemically Modified Gold-Based Superatoms"
    Shinjiro Takano, Shingo Hasegawa, Megumi Suyama, and Tatsuya Tsukuda*
    Acc. Chem. Res., 51, 3074-3083 (2018).
  13. 金超原子の化学　−ナノスケールの人工原子−
    14. 高野慎二郎・佃達哉
    現代化学, 553, 50-54 (2017).　
  14. "Controlled Synthesis of Carbon Supported Gold Clusters for Rational Catalyst Design"
    Seiji Yamazoe, Tatchamapan Yoskamtorn, Shinjiro Takano, Sudarat Yadnum, Jumras Limtrakul, and Tatsuya Tsukuda*
    Chem. Rec. 16, 2338-2348 (2016).
  15. Chapter2: "Controlled Synthesis: Size Control"
    16. Shinjiro Takano and Tatsuya Tsukuda
    in Protected Metal Clusters: From Fundamentals to Applications (1st Ed.), edited by Tatsuya Tsukuda and Hannu Häkkinen
    Elsevier, Amsterdam (2015).
  16. 極細金ナノワイヤーの精密合成とその光学特性
    17. 高野慎二郎・佃達哉
    化学と工業, 68, 1028 (2015).　
  17. 超原子と超原子分子: 金原子が つくるナノ構造体の美の世界
    18. 高野慎二郎・佃達哉
    化学と教育, 62, 602-605 (2014).　

依頼講演

  1. "配位子保護金クラスターの標的合成法の開拓と物性制御指針の探究", 第16回分子科学討論会2022横浜, 慶應義塾大学矢上キャンパス, 神奈川, 2022年9月
  2. "Targeted Synthesis of Ligand-Protected Gold Superatoms and Exploration of Their Design Principles", 日本化学会第102春季年会, オンライン, 2022年3月
  3. "Hydride-Doped Gold Clusters: Syntheses, Structures, and Transformations",
    4. The 76 th Fujihara Seminar
    International Workshop on Designer Nanocluster Materials -From Gas Phase to Condensed Phase-, Grand Hotel New Oji, Tomakomai, Hokkaido, Japan, Sep. 2019
  4. "保護された金クラスター:合成とその性質", 分子集積化学特論4, 東京理科大学神楽坂キャンパス, 東京, 2019年1月
  5. "Ligand protected gold cluster:Synthesis and Optical Property", ETHZ-UTokyo Joint Symposium of Frontier Chemistry, Tokyo, Japan, Nov. 2016
  6. "金クラスターの化学:精密合成とその応用",錯体化学若手の会　関東支部勉強会, 東京理科大学神楽坂キャンパス, 東京, 2016年5月.

競争的資金等

  1. 基盤研究B, 科学研究費補助金, 2023-2026.
  2. 田中貴金属記念財団 貴金属に関わる研究助成金 奨励賞, 2022.
  3. 池谷科学技術振興財団 研究助成金, 2019-2020.
  4. 若手研究, 学術研究助成基金助成金, 2019-2021.
  5. 特別研究員奨励費, 科学研究費補助金, 2014-2016.

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